Low temperature light off ammonia oxidation
AssigneeEngelhard Corporation
InventorsRobert J. Farrauto, Hyo C. Lee, W. Robert Hatfield
Life of this patent
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Abstract
Platinum-rhodium and platinum-palladium-rhodium gauzes bearing a high surface area coating (in excess of 50 cm.sup.2 /g) of platinum ease initiation of ammonia oxidation.
Claims19
A method of forming a catalytic gauze element comprising forming a woven mesh consisting essentially of platinum, rhodium and optionally palladium, grounding said mesh electrically, and spraying electrically charged droplets comprising a thermally decomposable platinum compound dispersed in a volatile liquid onto said mesh and thereafter evaporating said volatile liquid and decomposing said thermally decomposable platinum compound to form a high surface area coating of platinum upon said mesh, the surface area of the resulting coated mesh being at least about 50 cm.sup.2 /g.
A catalytic element comprising filaments consisting essentially of platinum, rhodium and optionally palladium, said filaments having a high surface area coating consisting essentially of platinum formed thereon, the surface area of said catalytic element exceeding 50 cm.sup.2 /g.
A method of forming a catalytic gauze element comprising forming a woven mesh consisting essentially of platinum, rhodium and optionally palladium, and spraying droplets comprising a thermally decomposable platinum compound dispersed in a volatile liquid onto said mesh and thereafter evaporating said volatile liquid and decomposing said thermally decomposable platinum compound to form a high surface area coating of platinum upon said mesh, the surface area of the resulting coated mesh being at least about 50 cm.sup.2 /g.
A method of forming a catalytic gauze element comprising forming a woven mesh consisting essentially of platinum, rhodium and optionally palladium, and depositing a thermally decomposable platinum compound dispersed in a volatile liquid onto said mesh and thereafter evaporating said volatile liquid and decomposing said thermally decomposable platinum compound to form a high surface area coating of platinum upon said mesh, the surface area of the resulting coated mesh being at least about 50 cm.sup.2 /g.
Dependencies are inferred from the claim text.