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US 4,857,228 AGranted
Phosphors and methods of preparing the same
AssigneeSunstone Corporation
InventorsGabriella H. Kabay, Ernest Kabay
Life of this patent
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Abstract
Phosphors based on a crystalline matrix of an alkaline earth and a chalcogen together with an activator system are prepared by a process which preferably includes exposure to both S and Se vapors. The phosphors have enhanced light output. IR-stimulable phosphors have stimulation quantum efficiencies above 5%, and preferably include Eu:Sm or Eu:Bi activator systems. Eu:Cu activators provide phosphorescent phosphors.
Claims22
An infrared stimulable phosphor consisting essentially of:
- (a) an alkaline earth sulfur selenium crystalline matrix the alkaline-earth metal selected from the group consisting of strontium, calcium and combinations thereof, wherein the molar ratio of S to Se is between about 1:10 and 10:1;
- (b) Eu as a first activator in an amount of about 5 to about 500 ppm by weight based on the weight of the matrix;
- and
- (c) Bi, Sm or combinations thereof, as a second activator each in an amount of about 5 to about 500 ppm by weight based on the weight of the matrix,
- said activators being dispersed within said matrix, said matrix and said activators cooperatively defining active sites adapted to store energy upon exposure of the phosphor to visible or ultraviolet light, said active sites being adapted to emit said stored energy as visible light upon exposure of the phosphor to infrared light, said phosphor including at least about 5.times.10.sup.17 of said active sites per cm.sup.3 and having a stimulation quantum efficiency of at least 5 percent.
2 more elements
Dependencies are inferred from the claim text.