Alkylation of organic aromatic compounds
AssigneeChemical Research & Licensing Company
InventorLawrence A. Smith, Jr.
Life of this patent
Estimating the term…
Abstract
Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.
Claims23
A method for controlling the concentration of olefin in the alkylation of organic aromatic compounds comprising:
- (a) concurrently
- (i) feeding a C.sub.2 to C.sub.20 olefin into a fixed bed acidic catalytic distillation structure in a distillation reaction zone located in a distillation column reactor and having process flow rates
- (ii) contacting said olefin with an organic aromatic compound having a boiling point higher than said olefin thereby catalytically reacting said organic aromatic compound and said olefin to form an alkylation product there being a temperature depression in said distillation column reactor at a point immediately above the point at which said olefin is fed thereto,
- (iii) determining the concentration of said olefin in said reactor at a given temperature depression at a given pressure,
- (iv) adjusting the process flows rate in the distillation column reactor to maintain a selected temperature at said depression point whereby a specific mole ratio of organic aromatic compound to olefin is maintained and
- (v) fractionating the resultant alkylation product and the unreacted organic aromatic compound and olefin in said fixed bed, and
- (b) withdrawing said alkylation product from said distillation column reactor at a point below said fixed bed.
Dependencies are inferred from the claim text.