Treatment of fibrous substrates, such as carpet, with fluorochemical
AssigneeMinnesota Mining and Manufacturing Company
InventorKalyanji U. Patel
Life of this patent
Estimating the term…
Abstract
Fluorochemical amine salt compounds containing one or more fluoroaliphatic radicals and one or more salt-forming amino groups which have cyanoalkyl groups as N-substituents groups, such compounds being useful as treating agents for fibrous substrates, such as textiles, e.g., carpet, to modify surface properties thereof, viz., to impart oil and water repellency to the surface of said substrates.
Claims6
Compounds of the formula ##STR28## where R.sub.f is a fluorinated, saturated, monovalent, aliphatic, stable, non-polar, inert, oleophobic, hydrophobic radical having 3 to 20 carbon atoms and 40 to 78 weight percent fluorine and terminating in at least three fully fluorinated carbon atoms;
- Q is an organic linking group which is one or a combination of polyvalent aliphatic groups, polyvalent aromatic groups, oxy (--O--), thio (--S--), carbonyl (--CO--), sulfonamido ##STR29## carbonamido ##STR30## hydroxymethylene (--CH(OH)--), carbamato (--NHCOO--) and urylene (--NHCONH) organic linking moieties, with the proviso that the moiety of Q which is bonded to the nitrogen atom of the amine salt group is not an electrophilic moiety and that Q is bonded to the nitrogen atom of the amine salt group by a methylene moiety;
- N is a tertiary amino nitrogen atom or quaternary amino nitrogen atom;
- R.sup.1 is a hydrogen or an alkyl group,
- R.sup.2 is R.sub.f Q--, alkyl groups, alkyl groups containing an --O-- hetero atom, alkyl groups containing an --S-- hetero atom, alkyl groups containing an ##STR31## hetero atom, aryl groups, aryl groups containing an --O-- hetero atom, aryl groups containing an --S-- hetero atom, aryl groups containing an ##STR32## hetero atom, combinations of such groups, alkylene groups, arylene groups or combinations of arylene and alkylene groups;
- R.sup.3 is a cyanoalkyl moiety;
- R.sup.4 is an alkylene or arylene group;
- A is an anion derived from a protonic acid or an alkylating agent;
- s is 1;
- y is 1 to 4;
- p is 0 to 1;
- z is 1 to 4;
- with the provisos that
- (1) when y is 1, then p is 0 and z is 1, and (2) when y is 2, then R.sup.2 is said alkylene or arylene group or combination thereof, and said compounds contain at least about 20 weight-percent carbon-bonded fluorine the locus of which is in said R.sub.f radical.
Compounds of the formula ##STR33## where R.sub.f is a stable, inert, non-polar, fluoroalkyl radical having 3 to 20 carbon atoms, 40 to 78 weight-percent fluorine, and a terminal portion having at least three fully fluorinated carbon atoms, said fluoroalkyl radical being selected from straight chain radicals, branched chain radicals, cyclic radicals, and combinations thereof;
- Q is an organic linking group which is one or a combination of polyvalent aliphatic groups, polyvalent aromatic groups, oxy (--O--), thio (--S--), carbonyl (--CO--), sulfonamido ##STR34## carbonamido ##STR35## hydroxymethylene (--CH(OH)--), carbamato (--NHCOO--) and urylene (--NHCONH) organic linking moieties, with the proviso that the moiety of Q which is bonded to the nitrogen atom of the amine salt group is not an electrophilic moiety and that Q is bonded to the nitrogen atom of the amine salt group by a methylene moiety;
- N is a tertiary amino nitrogen atom or quaternary amino nitrogen atom;
- R.sup.1 is a hydrogen or an alkyl group,
- R.sup.2 is R.sub.f Q--, alkyl groups, alkyl groups containing an --O-- hetero atom, alkyl groups containing an --S -- hetero atom, alkyl groups containing an ##STR36## hetero atom, aryl groups, aryl groups containing an --O-- hetero atom, aryl groups containing an --S-- hetero atom, aryl groups containing an ##STR37## hetero atom, combinations of such groups, alkylene groups, arylene groups or combinations of arylene and alkylene groups;
- R.sup.3 is CH.sub.2 CH.sub.2 CN;
- R.sup.4 is an alkylene or arylene group;
- A is an anion derived from a protonic acid or an alkylating agent;
- s is 1;
- y is 1 to 4;
- p is 0 to 2;
- z is 1 to 2;
- with the provisos that
- (1) when y is 1, then p is 0 and z is 1, and (2) when y is 2, then R.sup.2 is said alkylene or arylene group or combination thereof, and said compounds contain at least about 20 weight-percent carbon-bonded fluorine the locus of which is in said R.sub.f radical.
Compounds of the formula ##STR38## where R.sub.f is C.sub.n F.sub.2n+1 - wherein n is 3 to 20;
- Q is an organic linking group which is one or a combination of polyvalent aliphatic groups, polyvalent aromatic groups, oxy (--O--), thio (--S--), carbonyl (--CO--), sulfonamido ##STR39## carbonamido ##STR40## hydroxymethylene (--CH(OH)--), carbamato (--NHCOO--) and urylene (--NHCONH--) organic linking moieties, with the proviso that the moiety of Q which is bonded to the nitrogen atom of the amine salt group is not an electrophilic moiety and that Q is bonded to the nitrogen atom of the amine salt group by a methylene moiety;
- N is a tertiary amino nitrogen atom or quaternary amino nitrogen atom;
- R.sup.1 is a hydrogen or an alkyl group,
- R.sup.2 is alkyl groups, alkyl groups containing an --O-- hetero atom, alkyl groups containing an --S-- hetero atom, alkyl groups containing an ##STR41## hetero atom, aryl groups, aryl groups containing an --O-- hetero atom, aryl groups containing an --S-- hetero atom, aryl groups containing an ##STR42## hetero atom, combinations of such groups, alkylene groups, arylene groups or combinations of arylene and alkylene groups;
- R.sup.3 is CH.sub.2 CH.sub.2 CN;
- R.sup.4 is an alkylene or arylene group;
- A is an anion derived from a protonic acid or an alkylating agent;
- s is 1;
- y is 1 to 4;
- p is 0 to 2;
- z is 1 to 2;
- with the provisos that
- (1) when y is 1, then p is 0 and z is 1, and (2) when y is 2, then R.sub.2 is said alkylene or arylene group or combination thereof, and said compounds contain at least about 20 weight-percent carbon-bonded fluorine the locus of which is in said R.sub.f radical.
A compound of the formula ##STR43##
Dependencies are inferred from the claim text.