Hydroquinones
AssigneeCiba-Geigy Corporation
InventorFrederick H. Howell
Life of this patent
Estimating the term…
Abstract
New hydroquinones have the formula: ##STR1## wherein p is 1 or 2 and q is 0 or 1, provided that p+q is 1 or 2; R is a residue of formula: ##STR2## wherein Q is (i) -OX or (ii) -PO(OR.sub.11)((O).sub.x R.sub.11); and salts thereof with organic or inorganic acid bases. The groups X and R.sub.11 and x are defined hereinafter. The compounds of formula I are useful as stabilisers in photographic materials.
Claims8
A hydroquinone compound of the formula:
- ##STR14## wherein p is 1 or 2 and q is 0 or 1, provided that p+q is 1 or 2;
- R is a group of the formula ##STR15## wherein Q is a number selected from the groups:
- (i) --OX wherein X is R.sub.5 or COR.sub.7 wherein R.sub.5 is hydrogen or a straight or branched chain alkyl group having from 1 to 20 carbon atoms,
- R.sub.7 is hydrogen or a straight or branched chain alkyl group having from 1 to 20 carbon atoms, a straight or branched chain alkenyl group having from 3 to 20 carbon atoms, a cycloalkyl group having from 3 to 12 carbon atoms, an aralkyl group having from 7 to 13 carbon atoms or an unsubstituted or mono- or di-C.sub.1 -C.sub.4 -alkyl substituted aryl group having from 6 to 10 carbon atoms, and
- (ii) --PO(OR.sub.10)((O).sub.x R.sub.11) wherein X is 1, R.sub.10 and R.sub.11 are the same or different and each is hydrogen or a straight or branched chain alkyl group having from 1 to 20 carbon atoms,
- n is an integer from 2 to 20:
- k is 1 or 2;
- R.sub.2 and R.sub.3 are the same or different and each is a straight or branched chain alkyl group having from 1 to 5 carbon atoms;
- and
- R.sub.1 is a straight or branched chain alkyl group having from 1 to 8 carbon atoms, or a group of formula II as hereinbefore defined and, when R.sub.1 is a group of formula II, then R.sub.1 and R may be the same or different;
- or a salt thereof with an organic or inorganic acid or base.
A compound according to claim 1 wherein p, q, R, Q, R.sub.1, R.sub.2, R.sub.3, R.sub.5, R.sub.7, p, k and n are as defined in claim 9;
- and R.sub.10 and R.sub.11, when x is 1, are the same or different and each is hydrogen or a straight or branched chain alkyl group having from 1 to 20 carbon atoms;
- or a salt thereof.
The compound 2,5-bis-(8-n-butoxy-2,6-dimethyl)-oct-2-yl)-hydroquinone.
Dependencies are inferred from the claim text.