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US 4,834,947 AGranted
Reactor system for rapid kill gas injection to gas phase polymerization reactors
AssigneeMobil Oil Corporation
InventorsJohn E. Cook, Robert O. Hagerty, Frederick W. Jacob
Life of this patent
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Abstract
There is provided an improvement in a method for terminating a gas phase olefin polymerization reaction with a kill gas such as carbon monoxide or carbon dioxide. The improvement involves the use of a carrier gas to increase the rate of penetration of kill gas into the reaction medium. The improved method is particularly adaptable to a fluid bed reactor system.
Claims3
In a fluid bed reactor system for polymerizing olefin monomers to a polymer in the presence of a catalyst comprising a vertical gas phase reactor means which comprises:
- a reactant inlet means at a first end of the reactor means and a venting means, comprising a first valve means, at a second end thereof,
- a fluidizing medium recovery means comprising a recycle line means, which contains a second valve means, in gas communication with said reactor means adapted to recover a fluidizing medium from an upper section of said reactor means and to recycle it to a lower section of said reactor means,
- a compressor means powering said fluidizing medium recovery means, and
- a kill gas injection means for terminating the reaction under emergency conditions to maintain the temperature in the reactor means below the sintering temperature of the polymer,
- an improvement comprising a means of increasing the rate of penetration of the kill gas through the reactor means which comprises a means defining and containing a supply of a carrier gas, which is not a poison for the catalyst, connected to the kill gas injection means, the kill gas and the carrier gas being injected into the reactor at the first end thereof, and a compressor failure sensing means in operative connection with:
- said first valve means;
- said second valve means;
- said venting means and said means defining and containing the carrier gas.
5 more elements
Dependencies are inferred from the claim text.