Acid-curable composition containing a masked curing catalyst, and a process for its preparation
AssigneeCiba-Geigy Corporation
InventorsRudolf Kirchmayr, Werner Rutsch
Life of this patent
Estimating the term…
Abstract
Compounds of formula X ##STR1## in which R.sub.6 is aryl, R.sub.7 is hydrogen, --OH or alkyl, R.sub.8 is alkyl, R.sub.9 is hydrogen, alkyl, alkenyl, aryl, furyl or --CCl.sub.3, when n is 1, R.sub.10 is alkyl, aryl, camphoryl, --CF.sub.3 or fluoro, or when n is 2, R.sub.10 is alkylene or arylene are latent curing catalysts for acid-curable stoving varnishes. On irradiation, the active curing catalysts which lead to acid-catalysed curing of the resins are formed from the compounds of the formula x.
Claims14
A compound of the formula ##STR30## wherein R.sub.6 is unsubstituted phenyl, naphthyl, anthryl or phenanthryl, or phenyl or naphthyl substituted with from 1 to 3 substituents selected from the group consisting of chloro, bromo, C.sub.1 -C.sub.8 alkyl, phenyl, C.sub.1 -C.sub.8 alkoxy, phenoxy, benzyloxy, C.sub.1 -C.sub.8 alkylthio, phenylthio, 2-hydroxyethylthio, C.sub.1 -C.sub.4 alkylCONH, benzoylamino, dimethylamino, and benzoyl;
- R.sub.7 is hydroxy, C.sub.1 -C.sub.4 alkoxy, --OSi(CH.sub.3).sub.3, or acetoxy;
- R.sub.8, taken alone, is C.sub.1 -C.sub.8 alkyl or C.sub.1 -C.sub.8 alkyl substituted with phenyl;
- and
- R.sub.9, taken alone, is hydrogen;
- C.sub.1 -C.sub.8 alkyl unsubstituted or substituted with hydroxy, chloro, or phenyl;
- phenyl unsubstituted or substituted with hydroxy, chloro, C.sub.1 -C.sub.4 alkyl, or C.sub.1 -C.sub.4 alkoxy;
- C.sub.2 -C.sub.6 alkenyl;
- C.sub.8 -C.sub.9 phenylalkenyl;
- furyl;
- thienyl;
- trichloromethyl;
- C.sub.5 -C.sub.6 -cycloalkyl;
- or C.sub.5 -C.sub.6 cycloalkenyl;
- or
- R.sub.8 and R.sub.9, taken together, together with the carbon atoms to which they are attached, are a 5- or 6-membered saturated ring in which the remaining three to four ring members are selected from the group consisting of --CH.sub.2 --, --CH(CH.sub.3)--, and --C(CH.sub.3).sub.2 ;
- n has a value of 1 or 2;
- and
- when n is 1, R.sub.10 is C.sub.5 -C.sub.6 cycloalkyl;
- C.sub.7 -C.sub.9 aralkyl;
- camphoryl;
- trifluoromethyl;
- trichloromethyl;
- fluoro;
- amino;
- C.sub.1 -C.sub.18 alkyl;
- phenyl unsubstituted or substituted with chloro, hydroxy, C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylCONH, benzoyl amino, nitro, or benzoyl;
- or naphthyl, unsubstituted or substituted with chloro, C.sub.1 -C.sub.12 alkyl, or C.sub.1 -C.sub.4 alkoxy;
- or
- when n is 2, R.sub.10 is --(CH.sub.2).sub.m -- in which m has a value of 2 to 8;
- naphthylene;
- or phenylene unsubstituted or substituted with C.sub.1 -C.sub.12 alkyl.
Dependencies are inferred from the claim text.