Synthetic lamellar magnesium phyllosilicate and process for preparation thereof
AssigneeMizusawa Industrial Chemicals, Ltd.
InventorsKiochi Usui, Teiji Sato, Masanori Tanaka, Noriyuki Takahashi
Life of this patent
Estimating the term…
Loading patent…
AssigneeMizusawa Industrial Chemicals, Ltd.
InventorsKiochi Usui, Teiji Sato, Masanori Tanaka, Noriyuki Takahashi
Estimating the term…
A synthetic lamellar magnesium phyllosilicate has as the main component a composition represented by the following formula: Mg.sub.3 Si.sub.4 O.sub.10 (OH).sub.2.nH.sub.2 O (1) wherein n is a number of up to 5, and has X-ray diffraction peaks at spacings of 4.5-4.6 .ANG., 2.5-2.6 .ANG. and 1.5-1.6 .ANG., wherein the lamination asymmetry index (Is) defined by the following formula: Is=tan .theta..sub.2 /tan .theta..sub.1 (2) wherein .theta..sub.1 stands for the angle formed by the peak perpendicular and the peak tangent on the small diffraction angle side in said X-ray diffraction peak at a spacing of 4.5-4.6 .ANG., and .theta..sub.2 stands for the angle formed by the peak perpendicular and the peak tangent on the large diffraction angle side in said X-ray diffraction peak, is at least 3.0, the BET specific surface area is at least 300 m.sup.2 /g and the Methylene Blue decolorizing power (JIS K-1470) is at least 100 ml/g. This synthetic lamellar magnesium phyllosilicate is prepared by a process comprising subjecting active silicic acid or active aluminosilicic acid and an oxide or hydroxide of magnesium or a compound capable of forming said oxide or hydroxide under reaction conditions to a hydrothermal treatment.
Synthetic lamellar magnesium phyllosilicate, which has as the main component a composition represented by the following formula:
A process for the preparation of synthetic lamellar magnesium phyllosilicate, which comprises (i) subjecting an acid clay mineral belonging to the montmorillonite group to an acid treatment to such an extent that the X-ray diffraction peak of the plane index (001) of the clay mineral substantially disappears and the Al.sub.2 O.sub.3 /SiO.sub.2 molar ratio of the acid-treated product is within the range of from 1/11 to 1/99, the acid treatment being carried out using an acid or an aqueous solution of an acid in an amount of 0.3 to 1.5 equivalents to the basic components in the mineral, reacting the mineral with the acid at a temperature of 60.degree. to 300.degree. C. for 10 to 600 minutes and extracting the soluble basic component from the reaction product in an aqueous medium having a pH value smaller than 1 (ii) adjusting the particle size of the acid-treated product of the clay material so that particles having a particle size smaller than 5 .mu. occupy at least 20% by weight of the total particles and particles having a particle size larger than 20 .mu. occupy less than 30% by weight of the total particles, and (iii) subjecting the acid-treated product of the clay mineral and an oxide or hydroxide of magnesium or a compound capable of forming said oxide or hydroxide under reaction conditions to a hydrothermal treatment at an MgO/SiO.sub.2 molar ratio of from 2/4 to 6/4 at a temperature of 110.degree. to 200.degree. C. to form a synthetic lamellar phyllosilicate having as the main component a composition represented by the formula
Dependencies are inferred from the claim text.