Process for the co-production of aromatic carboxylates and alkyl iodides
AssigneeEastman Kodak Company
InventorsMark Rule, Thomas H. Larkins, Jr., Donald W. Lane, Guy R. Steinmetz
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Abstract
Disclosed is a process for the co-production of aromatic carboxylates and alkyl iodides by the carbonylation of aromatic iodides in the presence of an alkanol and a nickel catalyst.
Claims11
A process comprising producing a mixture of an aromatic carboxylic ester and an alkyl iodide by carbonylating an aromatic iodide in the presence of carbon monoxide, an alkanol and a catalytic amount of a nickel catalyst in the range of 10 to 0.001 mole percent under aromatic carboxylic ester and alkyl iodide forming conditions of temperature and pressure, and recovering said alkyl iodide so produced.
A process comprising producing mixture of an aromatic dicarboxylic ester selected from the group consisting of dimethyl benzenedicarboxylate and dimethyl naphthalenedicarboxylate and methyl iodide by carbonylating a diiodoaromatic compound selected from the group consisting of diiodobenzene and diiodonaphthalene in the presence of carbon monoxide, methanol, an organic co-solvent and a catalytic amount of a nickel catalyst in the range of 10 to 0.001 mole percent at a temperature of about 150.degree. to 200.degree. C. and a pressure of about 300 to 1,000 psig, and
- recovering the methyl iodide so produced.
A process comprising producing a mixture of dimethyl 2,6-naphthalenedicarboxylate and methyl iodide by carbonylating 2,6-diiodonaphthalene in the presence of carbon monoxide, methanol, an organic co-solvent and a catalytic amount of nickel in the range of 10 to 0.001 mole percent at a temperature of about 175.degree. C. and a pressure of about 750 psig, and
- recovering the methyl iodide so produced.
Dependencies are inferred from the claim text.