Liquid antioxidant produced by alkylating diphenylamine with a molar excess of diisobutylene
AssigneeCiba-Geigy Corporation
InventorJanet Franklin
Life of this patent
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Abstract
Process is described for the production of a liquid antioxidant composition by reaction of diphenylamine with diisobutylene comprising reacting diphenylamine with diisobutylene in a molar ratio of from 1:1.1 to 1:2.5 and in the presence of an acid activated earth catalyst, while ensuring that the concentration of diisobutylene remains substantially constant throughout the reaction period at a reaction temperature of at least 160.degree. C., the reaction being effected for such a period that the content of 4,4'-dioctyldiphenylamine in the reaction mass, excluding catalyst, is below 25% by weight; and removing catalyst and unreacted diisobutylene; the product of this process; and the use of this product as a stabilizer for organic material against oxidative degradation.
Claims14
Process for the production of a liquid antioxidant composition by reaction of diphenylamine with diisobutylene comprising
- reacting diphenylamine with diisobutylene in a molar ratio from 1:1.1 to 1:2.5 in the presence of an acid-activated earth catalyst, at a reaction temprature of at least 160.degree. C., the reaction being effected for such a period that the content of 4,4'-di-t-octyldiphenyl-amine in the final reaction mass, excluding catalyst, is below 25% by weight and that of diphenylamine is below 10% by weight;
- and
- removing catalyst and unreacted diisobutylene thereby producing the desired liquid antioxidant composition.
Liquid antioxidant composition produced by reacting diphenyl-amine with diisobutylene in a molar ratio of 1:1.1 to 1:2.5 in the presence of an acid-activated earth catalyst, at a reaction temperature of at least 160.degree. C., the reaction being effected for such a period that the content of 4,4'-di-t-octyldiphenylamine in the final reaction mass, excluding catalyst, is below 25% by weight and that of diphenylamine is below 10% by weight;
- removing catalyst and unreacted diisobutylene;
- and isolating the resulting product.
Dependencies are inferred from the claim text.