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US 4,820,446 AGranted
Electrically conductive, potentially adhesive composition
AssigneeCiba-Geigy Corporation
InventorChristian Prud'Homme
Life of this patent
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Abstract
The present invention relates to electrically conductive, potentially adhesive compositions and to films formed from these compositions which are capable of being employed in particular for the adhesive bonding of the surfaces of electronic devices. These compositions are characterized in that they comprise a thermoplastic block copolymer containing polysiloxane and urethane groups, with elastomeric properties and particles whose surface at least is electrically conductive and, if appropriate, a solvent or diluent.
Claims16
An electrically conductive, potentially adhesive composition which comprises
- (a) a thermoplastic block copolymer having elastic properties and consisting of polysiloxane and urethane groups with a concatenation of recurring repeat units of formula I and formula II
- --O--(X--O--CO--NH--Y--NH--CO--O).sub.m X--O-- (I)
- --CO--NH--(Y--NH--CO--O).sub.a --Z--(O--CO--NH--Y).sub.a --NH--CO--(II)
- in which
- Z, having the formula III, denotes a divalent radical bearing a polysiloxane block
- --L--Si(R.sub.2)--O--Si(R).sub.2 ].sub.n --L'-- (III)
- wherein
- L and L', which are identical or different, denote divalent radicals of formula IV
- --T--CHR.sub.1 --CR.sub.2 R.sub.3 -- (IV)
- where
- T denotes a divalent radical forming part of the molecular structure of an unsaturated isocyanate or an unsaturated alcohol of the formulae
- OCN--T--CR.sub.1 .dbd.CR.sub.2 R.sub.3
- or
- HO--T--CR.sub.1 .dbd.CR.sub.2 R.sub.3
- these radicals T being hydrocarbon in nature and containing 1 to 20 carbon atoms, or said radicals including one or more hetero atoms or groups chosen from oxygen, sulfur, silicon and nitrogen atoms and ester or amide groups,
- R.sub.1, R.sub.2 and R.sub.3 independently denote a hydrogen atom or an alkyl or aryl group, or R.sub.1 and R.sub.2 together are alkylene,
- R, which are identical or different, denote alkyl radicals containing 1 to 5 carbon atoms or said alkyl radicals containing 1 to 7 chlorine or fluorine atoms or mixture thereof;
- cycloalkyl containing 3 to 8 carbon atoms or said cycloalkyl radicals containing 1 to 4 chlorine or fluorine atoms or mixture thereof;
- alkenyl radicals containing 2 to 5 carbon atoms;
- aryl or alkylaryl radicals containing 6 to 8 carbon atoms, or said aryl radicals containing 1 to 4 chlorine or fluorine atoms or mixture thereof;
- n is a number from to 1000,
- X and Y denote divalent radicals of hydrocarbon nature corresponding, respectively, to the diol X(OH).sub.2 and to the diisocyanate Y(NCO).sub.2, each containing 2 to 20 carbon atoms,
- m denotes a number from 1 to 20, and
- z is zero or 1, and
- (b) an effective amount, sufficient to afford electrical conductivity to the composition, of particles with at least the surface of said particles being electrically conductive.
22 more elements
Dependencies are inferred from the claim text.