Process and installation for the adsorptive separation of krypton from a krypton nitrogen gas mixture

In a process for the adsorptive separation of krypton from a gas mixture especially containing nitrogen in addition to the krypton, in an adsorption column, wherein the column is filled over a length L extending along the direction of the inflowing gas mixture with an adsorption medium which adsorbs krypton and nitrogen, and desorbed with a gaseous scavenging medium after adsorption of the gas constituents, scavenging medium flowing through the adsorption column in the same direction as the gas mixture and, said process consisting essentially of an adsorptive step and a desorptive step;

• the improvement comprising:
• filling in the adsorption medium through a gas inlet of the adsorption column commencing with krypton over only a partial length L.sub.O of the overall column length L whereby, during desorption of the adsorption column, there is separately withdrawable together with the scavenging medium from a gas discharge of the adsorption column initially only nitrogen, and subsequently krypton, said adsorption column being charged with said gas mixture with the gas discharge closed up to a predetermined gas pressure;
• the introduction of the gas mixture being blocked upon reaching said predetermined gas pressure;
• the desorption of said adsorption column being conducted at atmospheric pressure and with the gas discharge opened;
• and the scavenging gas containing nitrogen being conveyed from the gas discharge into a nitrogen conduit, and thereafter the scavenging gas containing krypton being conveyed into a krypton conduit.