Process for the dimerization of olefins
AssigneeShell Oil Company
InventorEit Drent
Life of this patent
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Abstract
A process for the dimerization of alpha-alkenes having 2 to 12 carbon atoms in the presence of an alkanediol solvent and of a novel catalytic system formed by combining: (a) a palladium(II) compound, (b) a chelate ligand comprising a compound containing at least two N coordinating atoms which are connected through a chain comprising two C atoms, >2.0 mol chelate ligand per gram-atom Pd being used, (c) a protonic acid, except hydrohalogenic acids, and (d) a salt of Cu, Fe, Zn, Sn, Mn, V, Al or a Group VIB metal, except a halide.
Claims18
A process for the dimerization in the liquid phase of an alpha-alkene which comprises contacting an alpha-alkene having in the range of from 2 to 12 carbon atoms per molecule with an alkanediol solvent in the presence of a catalytic system formed by combining:
- (a) a palladium(II) compound,
- (b) a chelate ligand comprising a compound containing as coordinating atoms at least two nitrogen atoms which are connected through a chain comprising two carbon atoms, wherein more than about 2.0 mol of said chelate ligand per gram-atom of palladium(II) is used,
- (c) a protonic acid, with the exception of a hydrohalogenic acid, and
- (d) a salt of a protonic acid selected from the group consisting of copper, iron, zinc, tin, manganese, vanadium, aluminum, a metal of Group VIB of the Periodic Table of the Elements and mixtures thereof, with the exception of a halide.
Dependencies are inferred from the claim text.