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AssigneeElectrolytic Zinc Company of Australia Limited
InventorsOliver M. G. Newman, Alan M. Bond, Robert W. Knight
Estimating the term…
A method and apparatus for determining electrochemically active components in a process stream. The method comprises the steps of providing a sample in which the components are contained, and depositing the components onto a working electrode, altering the environment of the working electrode so that it is immersed in a supporting electrolyte by effecting a matrix exchange and stripping the deposited electrochemically active components from the working electrode into the supporting electrolyte. The method and apparatus utilize a measurement cell which comprises a vessel (10) for containing the supporting electrolyte and a mercury drop electrode (150). A flow injector (16) is used to inject a flow of a sample electrolyte which contains the electrochemically active component; and into the vessel so that the sample electrolyte surrounds the mercury drop electrode and then sinks away from the mercury drop electrode (150) to the bottom of the vessel where it is removed via an outlet (20) to thereby leave the mercury electrode (150) immersed in the supporting electrolyte. The deposited impurities are stripped from the working electrode using variable time domain transient electrochemical stripping voltammetry. The sequence of steps including the deposition of the impurities from an injected flow of electrolyte sample are repeated under microprocessor control (50).
A method for the determination of electrochemically active components in a process stream comprising the steps of immersing a working electrode in a supporting electrolyte, injecting a flow of a sample solution of the stream containing an electrochemically active component onto said working electrode so that the electrode is now surrounded with the sample solution to deposit said component onto the working electrode, said supporting electrolyte being less dense than said sample solution, stopping the flow of injected sample solution so that the sample solution sinks away from the working electrode to leave the working electrode having the component deposited thereon again immersed in the supporting electrolyte to thereby effect a matrix exchange, stripping the deposited component from the working electrode into the supporting electrolyte and determining the presence of the component in the supporting electrolyte.
A method for the determination of impurities in an electrolyte containing a much higher concentration of another electrochemically active species characterized by the automated and continual performance of a series of sequential steps which are repeated under microprocessor control, said sequence of steps comprising depositing said impurities from an injected flow of an electrolyte sample containing the impurities onto a mercury electrode immersed in a supporting electrolyte which is less dense than the sample electrolyte, stopping the flow of injected sample electrolyte and finally effecting a matrix exchange by stripping the deposited impurities from the mercury electrode into the less dense supporting electrolyte using variable time domain transient electrochemical stripping voltammetry and determining the presence of the impurities in the supporting electrolyte.
An apparatus for the determination of impurities in an electrolyte containing a much higher concentration of another electrochemically active species comprising a measurement cell for holding a supporting electrolyte, means for forming a mercury electrode to be immersed in said supporting electrolyte, means for injecting a flow of a sample of the electrolyte containing said impurities onto said mercury electrode, said means for injecting the flow of sample electrolyte including a flow nozzle arranged adjacent to said mercury electrode when said mercury electrode is formed, said flow nozzle injecting the sample electrolyte towards the mercury electrode so that the sample electrolyte displaces said supporting electrolyte surrounding the mercury electrode so that the mercury electrode is surrounded by the sample electrolyte whilst both said sample electrolyte and said mercury electrode are within the supporting electrolyte, means for energizing said mercury electrode to cause said impurities to be deposited thereon, means for stopping the injection of the sample electrolyte from the flow nozzle so that the sample electrolyte moves away from said mercury electrode to leave the mercury electrode surrounded by the supporting electrolyte to thereby effect a matrix exchange, means for again energizing said mercury electrode so as to strip deposited impurities from the mercury electrode into the supporting electrolyte using variable time domain transient electrochemical stripping voltammetry and microprocessor control means for automating in sequence the injecting means, the stopping means and the energizing means.
Dependencies are inferred from the claim text.