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US 4,798,674 AGranted
Separation of organic liquids
AssigneeTexaco Inc.
InventorsMordechai Pasternak, Craig R. Bartels, John Reale, Jr.
Life of this patent
Estimating the term…
Abstract
Mixtures containing methanol and dimethyl carbonate or methanol and methyl t-butyl ether may be treated by pervaporation to recover product containing decreased quantity of methanol.
Claims9
The method comprising:
- concentrating a charge solution containing
- (i) an alcohol having less than three carbon atoms and
- (ii) an oxygenate selected from the group consisting of organic ethers, aldehydes, ketones, and esters by,
- maintaining a non-porous membrane separating layer selected from the group consisting of
- (i) polyvinyl alcohol which has been crosslinked with an aliphatic polyaldehyde containing at least three carbon atoms including those in said aldehyde groups;
- and
- (ii) high molecular weight ion exchange resin in membrane form having carbon atoms in the backbone bearing a pendant acid group, which membrane has been contacted with a quaternary ammonium salt containing four hydrocarbyl groups;
- maintaining a pressure drop across said non-porous separating layer;
- passing a charge aqueous solution containing (i) an alcohol having less than three carbon atoms and (ii) an oxygenate selected from the group consisting of organic ethers, aldehydes, ketones, and esters into contact with the high pressure side of said non-porous separating layer having properties which enable at least a portion of said alcohol in said charge solution and a lesser portion of oxygenate to pass by pervaporation through said non-porous separating layer as a lean mixture containing more alcohol and less oxygenate than are present in said charge solution and said charge solution is converted to a rich liquid containing less alcohol and more oxygenate than are present in said charge solution;
- recovering as permeate from the low pressure side of said non-porous separating layer said lean mixture containing more alcohol and less oxygenate than are present in said charge solution, said lean mixture being recovered in vapor phase at a pressure below the vapor pressure thereof;
- and
- recovering as retentate from the high pressure side of said non-porous separating layer said rich liquid containing a lower alcohol content and a high oxygenate content than are present in said charge solution.
9 more elements
The method comprising:
- concentrating a charge solution containing methanol and either dimethyl carbonate or methyl t-butyl ether oxygenate by,
- maintaining a membrane of non-porous separating layer of cast polyvinyl alcohol which has been crosslinked with an aliphatic polyaldehyde containing at least three carbon atoms including those in said aldehyde groups;
- maintaining a pressure drop across said non-porous separating layer of polyvinyl alcohol;
- passing a charge aqueous solution containing methanol and either dimethyl carbonate or methyl t-butyl ether oxygenate into contact with the high pressure side of said non-porous separating layer of polyvinyl alcohol having properties which enable at least a portion of said methanol in said charge solution and a lesser portion of oxygenate to pass by pervaporation through said non-porous separating layer of polyvinyl alcohol as a lean mixture containing more methanol and less oxygenate than are present in said charge solution and said charge solution is converted to a rich liquid containing less methanol and more oxygenate than are present in said charge solution;
- recovering as permeate from the low pressure side of said non-porous separating layer of polyvinyl alcohol said lean mixture containing more methanol and less oxygenate than are present in said charge solution, said lean mixture being recovered in vapor phase at a pressure below the vapor pressure thereof;
- and
- recovering as retentate from the high pressure side of said non-porous separating layer said rich liquid containing a lower methanol content and a higher oxygenate content than are present in said charge solution.
4 more elements
Dependencies are inferred from the claim text.