Fluorinated carbocylic compounds
AssigneeOccidental Chemical Corporation
InventorsJoseph F. Bieron, David Y. Tang
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AssigneeOccidental Chemical Corporation
InventorsJoseph F. Bieron, David Y. Tang
Estimating the term…
Fluoro-substituted carbocyclic compounds are prepared by (A) reacting hydrogen fluoride with a chloro-cyclohexenyl compound of the formula ##STR1## where R.sub.1 and R.sub.2 are independently selected from the group consisting of --H, --CH.sub.2 OH, --COF, --COCl, --CF.sub.3, --CN, ##STR2## and --CH.sub.2 R, where R is --H or alkyl of 1-4 carbon atoms, to form a gem-dihalocyclohexane compound of the formula ##STR3## where X is chlorine and R.sub.1 and R.sub.2 are as defined above, (B) dehydrohalogenating the gem-dihalocyclohexane compound in the vapor phase to form a fluoro-cyclohexenyl compound of the formula ##STR4## (C) contacting the fluoro-cyclohexenyl compound, in the vapor phase, with a dehydrogenation catalyst to form a fluoro-substituted aromatic compound of the formula ##STR5##
A gem-dihalocyclohexane compound of the formula ##STR28## wherein X is chlorine or fluorine and R.sub.1 and R.sub.2 are independently selected from the group consisting of --H, --CH.sub.2 OH, --COF, --COCl, --CF.sub.3, --CN, ##STR29## and --CH.sub.2 CH.sub.2R, wherein R is --H or alkyl of 1-4 carbon atoms;
A compound of the formula ##STR30##
A compound of the formula ##STR31##
A compound of the formula ##STR32##
A compound of the formula ##STR33##
A compound of the formula ##STR34##
A gem-dihalocyclohexane compound of the formula ##STR35## wherein X is chlorine or fluorine and R.sub.1 is --H and R.sub.2 is selected from the group consisting of --CH.sub.2 OH, --COF, --CF.sub.3, CN, ##STR36## and --CH.sub.2 CH.sub.2R, wherein R is --H or alkyl or 1-4 carbon atoms.
A gem-dihalocyclohexane compound of the formula ##STR37## wherein X is chlorine or fluorine and R.sub.1 is selected from the group consisting of --CH.sub.2 OH, --COF, --COCl, --CF.sub.3, --CN, ##STR38## and --CH.sub.2 CH.sub.2R, wherein R is --H or alkyl or 1-4 carbon atoms and R.sub.2 is H.
Dependencies are inferred from the claim text.