Heat sensitive recording material
AssigneeNippon Gohsei Kagaku Kogyo Kaboshiki Kaisha
InventorsNobuyuki Yamamoto, Isamu Nishikawa, Osamu Honmura
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AssigneeNippon Gohsei Kagaku Kogyo Kaboshiki Kaisha
InventorsNobuyuki Yamamoto, Isamu Nishikawa, Osamu Honmura
Estimating the term…
A heat sensitive recording material comprising (A) a color forming substance, (B) a developer capable of bringing the color forming substance into color image by heating and (C) a binder, characterized in that the component (B) comprises at least one diphenyl compound having the formula (I): ##STR1## The heat sensitive recording material can give satisfactory color sensibility, color density and printability in recording process at low temperature and high speed compared to conventional heat sensitive recording materials. Further, there are wholly observed the black fog on the surface of recording paper before recording and the black spot in contact with diazo photosensitive papers.
A heat sensitive recording material comprising a recording layer on a substrate, said recording layer comprising (A) a color forming substance, (B) a developer capable of bringing the color forming substance into color image by heating, and (C) a binder, characterized in that the component (B) comprises at least one diphenyl compound having the formula (I):
Dependencies are inferred from the claim text.
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Non-macromolecular compounds: compounds containing phenolic or carboxylic acid groups or metal salts thereof
Stock material or miscellaneous articles: material designed to be responsive to temperature, light, moisture
Printing, duplicating, marking, or copying processes
Technical subjects covered by former uspc cross-reference art collections [xracs] and digests
Term ended 27 Apr 2007 (estimated)
USPTO file history isn’t available for this patent, so only indexed dates are shown.
The present invention relates to a material suitable for heat sensitive recording papers, and more particularly to a heat sensitive recording material characterized by containing a specific developer capable of bringing a color forming substance into color images by heating.
The heat sensitive recording paper is a recording material in which a heat sensitive layer which can be developed a color by heating is applied to a surface of a substrate such a paper. The recording process is conducted by using a printer such as a thermal printer. The paper is widely utilized in the field of computers, facsimile telegraphs, calculating machines, and the like.
The heat sensitive layer is composed of a composition containing a color forming substance, a developer capable of bringing the color forming substance into color images and a binder, and it is said that the developer is the most influential component to properties of the heat sensitive recording material among the above three components. Accordingly the utility of the heat sensitive recording materials depends on the properties of the used developer.
______________________________________ Dispersion (A) Crystal Violet lactone 7 parts 10% aqueous solution of PVA 10 parts (polyvinyl alcohol commercially available under the commercial name of "GOHSENOL GL-05" made by Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha) Stearic acid amide 10 parts Calcium carbonate 25 parts Water 60 parts Dispersion (B) Benzyl bis(3-chloro-4-hydroxyphenyl)acetate 25 parts having the formula: ##STR14## 10% aqueous solution of PVA 10 parts Calcium carbonate 25 parts Solution (C) 10% aqueous solution of PVA 110 parts ______________________________________
The dispersions (A) and (B) and the solution (C) were prepared separately, each of the dispersions (A) and (B) was pulverized by using a sand grinder until average particle sizes of solid matters were from 2 to 3.mu., and the dispersions (A) and (B) and the solution (C) were mixed. The mixture was coated on a paper having a basis weight of 50 g/m.sup.2 so that an amount of coating was 10 g/m.sup.2 on the base of solid and was dried to give a heat sensitive recording paper.
The physical properties of the obtained heat sensitive recording paper are shown in Table 1.