Transparent infrared absorbing glass and method of making
AssigneePPG Industries, Inc.
InventorsGeorge A. Pecoraro, Larry J. Shelestak
Life of this patent
Estimating the term…
Abstract
A glass product having high visible transmittance, low infrared transmittance, and, optionally, reduced ultraviolet transmittance is produced in a manner compatible with continuous, commercial manufacture of flat glass by employing a moderate amount of iron in the glass composition and controlling reducing conditons to maintain a relatively large portion of the iron in the ferrous state.
Claims32
A method of manufacturing soda-lime-silica flat glass in a continuous process including feeding raw materials to a melting operation that includes separate liquefying and refining stages, passing from the melting operation to a flat glass forming operation a continuous stream of molten glass having at least 0.45 percent by weight iron expressed as Fe.sub.2 O.sub.3, forming the glass into a flat glass product in the forming operation, melting the raw materials in a thin layer in the liquefying stage while controlling oxidation-reduction conditions in that stage and in subsequent stages so as to yield a glass having at least 35 percent of the iron in the ferrous state expressed as FeO and which when formed into a flat glass product of suitable thickness exhibits the combination of luminous transmittance of at least 65 percent and infrared transmittance of no more than 15 percent.
A soda-lime-silica glass article having a composition consisting essentially of, on a weight basis:
- 66 to 75% SiO.sub.2, 12-20% Na.sub.2 O, 7-12% CaO, 0-5% MgO, 0-4% Al.sub.2 O.sub.3, 0-3% K.sub.2 O, 0.45-1% Fe.sub.2 O.sub.3, 0-1.5% total of CeO.sub.2, TiO.sub.2, V.sub.2 O.sub.5 or MoO.sub.3, at least 50 percent of the iron being in the ferrous state expressed as FeO, less than 0.02 percent by weight sulfur expressed as SO.sub.3, and exhibiting luminous transmittance of at least 65 percent and total solar infrared transmittance of no more than 15 percent at a selected thickness.
Dependencies are inferred from the claim text.