Desalination of saline water
AssigneeAllied-Signal Inc.
InventorsRaymond J. Swedo, Joseph J. Zupancic
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AssigneeAllied-Signal Inc.
InventorsRaymond J. Swedo, Joseph J. Zupancic
Estimating the term…
Saline water containing a chlorine-containing compound in the form of free chlorine, hypochlorite, etc. which has been added as a disinfectant or antibacterial compound is desalinated by passing the saline water through a semipermeable membrane which is resistant to the chlorine. The saline water is passed through this membrane at a temperature in the range of from ambient to about 50.degree. C. and a pressure in the range of from about 1380 to about 6895 kPA (200-1000 psi). The chlorine-resistant semipermeable membrane comprises an interfacial polymerized condensation reaction product composited on a porous backing support material which has been prepared by contacting a porous support material such as polysulfone with a solution of a diaryl methylene monomer containing at least one amine radical on each aryl nucleus. The coated support material is then contacted with an organic solvent of an aromatic carboxylic acid chloride for a period of time sufficient to form an interfacial polymerized reaction product on the surface of the support material. Following this the composite is then cured at an elevated temperature to form the desired membrane.
A process for the desalination of a saline water feedstream in the presence of an added chlorine-containing compound which comprises contacting said feedstream with the upstream face of a chlorine-resistant semipermeable membrane comprising a porous support backing material having composited thereon an interfacial polymerized condensation product resulting from the condensation reaction of a diaryl methylene monomer containing at least one amine radical on each aryl nucleus and an aromatic carboxylic acid chloride at separation conditions and recovering the resultant desalinated water downstream subsequent to passage through said membrane.
A chlorine-resistant semipermeable membrane which comprises a porous support backing material having composited thereon an interfacial polymerized condensation product resulting from the reaction of a diaryl methylene monomer containing at least one amine radical on each aryl nucleus and an aromatic carboxylic acid chloride.
A process for the preparation of a chlorine-resistant semipermeable membrane which comprises casting a solution of diaryl methylene monomer containing at least one amine radical on each aryl nucleus on a porous support backing material, removing excess solution, contacting the coated support with an organic solvent solution of an aromatic carboxylic acid chloride to form an interfacial polymerized condensation reaction product on the surface of said porous support backing material, removing excess solution, curing the resultant composite at curing conditions, and recovering the resultant chlorine-resistant semipermeable membrane.
Dependencies are inferred from the claim text.