Crystalline layered material MCM-20 and process for its preparation
AssigneeMobil Oil Corporation
InventorsPochen Chu, Guenter H. Kuehl, Michael E. Landis
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Abstract
Layered silicate materials of high thermal stability and surface area which contain interspathic oxides such as silica as prepared by treating a layered silicate, with organic cation, to spread the layers apart. A compound such as tetraethylorthosilicate, capable of forming said oxide, is thereafter introduced between the layers. The resulting product is treated to form the oxide, e.g. by hydrolysis, to produce the layered silicate material. The resulting product may be employed as a catalyst material in the conversion of hydrocarbons.
Claims11
A pillared silicate composition comprising
- a layered silicate, which exhibits an X-ray diffraction pattern of Table 1 of the specification;
- and
- (1) at least one oxide of an element from group IB, IIB, IIIA, IIIB, IVA, IVB, VA, VB, VIA, VIIA and VIIIA of the Periodic Table;
- (2) precursors of said at least one oxide;
- or
- (3) mixtures of (1) and (2);
- where said (1), (2) or (3) is interposed between layers of said layered silicate, to separate and support said layers.
A silicate composition comprising a layered silicate, which exhibits an X-ray diffraction pattern of Table 1 of the specification;
- and silica, tetraalkylorthosilicate;
- hydrolysis products of tetraalkylorthosilicate, or admixtures of silica and either tetraalkylorthosilicate or hydrolysis products of tetraalkylorthosilicate or both, interposed between laminae of said layered silicate to separate and support said laminae.
Dependencies are inferred from the claim text.