Films, layers, tapes, plates and similar structures of non-wettable plastic material coated with a wettable polyfluorocarbon film wherein the polyfluorocarbon has the formula (CF.sub.x).sub.n, where x has a value within the range of from 0.3 to about 1.4 and the polyfluorocarbon film is non-porous, adheres to the surface of said plastic material structure without the interposition of other materials, has a thickness ranging from 100 .ANG. to 3 microns, and has a critical surface tension which ranges from about 23 to about 34 dynes cm.sup.-1, said polyfluorocarbon film being obtained directly on the plastic material substrate by the plasma-polymerization of gaseous streams of C.sub.2 F.sub.6 and H.sub.2 ;
- or C.sub.2 F.sub.6 and C.sub.2 F.sub.4 ;
- or CF.sub.4 and H.sub.2 ;
- or CF.sub.4 and C.sub.2 F.sub.4 ;
- or C.sub.2 F.sub.4.