Oxyiodination catalyst
AssigneeEastman Kodak Company
InventorMark Rule
Life of this patent
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Abstract
Disclosed is a process for iodinating an aromatic compound over a zeolite catalyst containing a deactivation modifier selected from the group consisting of ions or salts of hydrogen, copper, zinc, cadmium, silver and mercury.
Claims9
A process for preparation of mono and diiodo benzene, naphthalene or diphenyl by iodinating a fluoro, chloro, bromo, iodo, hydroxy, or cyclo substituted benzene, naphthalene or diphenyl, which comprises reacting, at a temperature in the range of 100.degree. to 500.degree. C., a source of iodine with the substituted benzene, naphthalene or diphenyl in the presence of molecular oxygen over a zeolite catalyst with a pore size of 6 angstroms or greater and greater than ten percent of the exchangeable cations being alkali, alkaline earth or rare earth metal cations, wherein said catalyst contains an amount of a modifier effective to substantially prevent deactivation of said catalyst by alkyl substituted aromatic compounds, said modifier being selected from the group consisting of hydrogen, copper, zinc, cadmium, silver, and mercury ions or salts thereof.
A process for iodinating benzene or naphthalene, which comprises reacting, at a temperature in the range of 200.degree. to 400.degree. C., a source of iodine with benzene or naphthalene in the presence of air over a zeolite catalyst, wherein said catalyst contains 0.01 to 5.0 weight % of a modifier effective to substantially prevent deactivation of said catalyst by alkyl substituted aromatic compounds, said modifier being selected from the group consisting of hydrogen, copper, zinc, cadmium, silver, and mercury ions or salts thereof.
Dependencies are inferred from the claim text.