Epoxidized isocyanates and process for their preparation
AssigneeAmerican Cyanamid Company
InventorPaul S. Waterman
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Abstract
A process is disclosed for preparation of novel epoxy-substituted aralkyl isocyanates by reaction of tertiary aralkyl olefins and an epoxidizing agent at a temperature of from -35.degree. C. to about 50.degree. C. The compounds are useful as intermediates to produce curing agents for polyfunctional active hydrogen-containing compounds, e.g., by reaction with polyols to produce epoxy-pendant urethanes and then with polyamines, and the like.
Claims9
A process for preparation of a compound selected from those of the formulae:
- ##STR7## or a mixture of (I) and (II), said process comprising reacting (a) a tertiary aralkyl isocyanate of the formulae:
- ##STR8## or a mixture of any of (III) and (IV), with (b) an effective amount of an epoxidizing agent of the general formula
- ROOH
- wherein R is selected from ##STR9## wherein R.sup.1 and R.sup.2 are independently selected from alkyl and halo-substituted alkyl of 1 to 12 carbon atoms and aryl and halo substituted aryl-alkaryl, halo-substituted alkaryl, aralkyl and halo-substituted aralkyl of from 1 to 12 carbon atoms;
- in
- (c) an inert organic solvent at a temperature of from about -35.degree. C. to about 50.degree. C. until formation of (I) or (II) or a mixture of (I) and (II) is substantially complete.
A compound selected from those of the formulae:
- ##STR10## or a mixture of (I) and (II).
A compound of the formula:
- ##STR11##
A compound of the formula:
- ##STR12##
Dependencies are inferred from the claim text.