1-Diorganocarbamoyl-polyalkylpiperidines
AssigneeCiba-Geigy Corporation
InventorFriedrich Karrer
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Abstract
Compounds containing a group of the formula I ##STR1## in which R is H or C.sub.1 -C.sub.4 -alkyl, R.sup.1 is H, CN, an acyloxy group or a free valency and R.sup.2 and R.sup.3 are organic radicals can be prepared in a simple manner from the corresponding compounds containing a group of the formula Ia ##STR2## by stepwise reaction with phosgene and a secondary amine R.sup.2 --NH--R.sup.3 in the presence of a molar amount of a base. The N-diorganocarbamoyl compounds containing the group I are outstanding light stabilizers, in particular for organic polymers. They can be converted by secondary reactions into other compounds which contain the group I and which are not accessible by direct phosgenation. Many of the products thus obtainable by phosgenation or conversion are novel compounds.
Claims1
A compound of the formula VI ##STR37## wherein R is hydrogen;
- R.sup.2 and R.sup.3 independently are C.sub.1 -C.sub.18 -alkyl;
- or R.sup.2 and R.sup.3, together with the Natom to which they are bonded, form a piperidine, pyrrolidine, morpholine, or 4-alkylpiperidine ring;
- and R.sup.5 is a divalent acyl radical of an aliphatic or cycloaliphatic dicarboxylic acid.
Dependencies are inferred from the claim text.