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US 4,788,042 AGranted
System for conversion of methanol to gasoline
AssigneeMobil Oil Corporation
InventorsSusan K. Marsh, Hartley Owen, Bernard S. Wright
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Abstract
A methanol-to-gasoline (MTG) catalytic conversion system in which the conversion is conducted in a fixed bed catalytic reactor. A C.sub.3 -C.sub.4 hydrocarbon diluent is generated from pressurized liquid effluent and recycled to the fixed bed reactor in order to dissipate the heat of reaction.
Claims1
An apparatus for producing gasoline boiling range hydrocarbons from C.sub.1 to C.sub.3 oxygenates comprising:
- (a) a fixed bed reaction zone containing a crystalline zeolite catalyst;
- (b) means for transporting the reactor effluent from a reaction zone to a separation zone;
- (c) phase separator means wherein the reactor effluent is split into a gas stream, a water stream, and a liquid hydrocarbon stream;
- (d) means for transporting the liquid hydrocarbon stream to a heat exchange evaporator;
- (e) a heat exchange evaporator wherein the liquid hydrocarbon stream is partially vaporized;
- (f) means for transporting said partially vaporized stream to an accumulator;
- (g) an accumulator operatively connected as the first stage of a fractionating column wherein a vapor phase comprising C.sub.3 -C.sub.4 saturated hydrocarbons is separated from a liquid phase;
- (h) means for passing said liquid phase to a gasoline stripping zone;
- (i) a gasoline stripping zone wherein a stabilized gasoline product is prepared;
- (j) means for conducting said vapor phase from (g) to a further heat exchange evaporator;
- (k) a heat exchange evaporator wherein said vapor phase is heated to a temperature sufficient for entrance into a fixed bed reaction zone;
- (l) means for passing said heated vapor phase to a mixing zone;
- (m) a mixing zone wherein said heated vapor phase comprising C.sub.3 -C.sub.4 saturated hydrocarbons is combined with an oxygenate feedstock;
- and
- (n) means for passing said mixture to the fixed bed reaction zone of step (a).
12 more elements
Dependencies are inferred from the claim text.