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US 4,786,750 AGranted
Pentene derivatives
AssigneeICI Americas Inc.
InventorsRichard V. Nelson, John F. Stephen
Life of this patent
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Abstract
A method of preparing certain 2-halo-5-methylpyridines, useful as herbicide intermediates, is presented starting from acyclic pentenes. The pentene is difunctionalized, e.g., by making the epoxide, and is then reacted with a nitrogen source to close the ring. The nitrogen-containing 6-membered heterocycle may then be aromatized readily to produce the 2-halo-5-methylpyridine desired. Also part of the invention are novel acyclic and cyclic intermediates used in the process.
Claims1
A pentene derivative of the following formula III:
- ##STR8## wherein R is C.sub.1-6 alkoxy group;
- and R.sup.1 is hydroxy and R.sup.2 is bromine.
Dependencies are inferred from the claim text.