Process for polymer production
AssigneePolysar Limited
InventorDouglas C. Edwards
Life of this patent
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Abstract
A process is provided for the production of a polymer of reduced molecular weight by subjecting, in bulk form, a halogenated butyl polymer having at least 75 percent of the unsaturation in the EXO methylene configuration to mastication in an extruder while exposing the masticated polymer to an atmosphere containing ozone. Such reduced molecular weight polymers have an M.sub.n of from about 10,000 to about 40,000 and may be used in caulks and sealants.
Claims13
A continuous process for producing a polymer of reduced molecular weight which comprises subjecting a halogenated butyl polymer selected from chlorinated butyl rubber and brominated butyl rubber and having a number average molecular weight (M.sub.n) of from about 85,000 to about 150,000 to mastication in an extruder at a temperature of from about 140.degree. to about 200.degree. C. while being exposed to and in contact with an atmosphere containing from about 0.1 to about 4 volume per cent of ozone for a time sufficient to produce a reduced molecular weight polymer wherein the halogenated butyl polymer contains at least about 75 percent of the unsaturation in the EXO methylene configuration, said extruder is selected from twin screw and single screw extruders, said mastication is characterized by a shear rate of at least about 575 to about 1900 sec.sup.-1, and said reduced molecular weight polymer has an M.sub.n of from about 10,000 to about 40,000.
Dependencies are inferred from the claim text.