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US 4,785,050 AGranted
High impact strength, readily flowing polyamide moulding materials
AssigneeBayer Aktiengesellschaft
InventorsDieter Wittmann, Christian Lindner, Ludwig Trabert, Rudolf Binsack, Karl-Heinz Ott
Life of this patent
Estimating the term…
Abstract
Readily processable moulding materials with improved impact strength of polyamides and graft products which have a particular chemical and physical structure.
Claims6
A thermoplastic moulding material comprising,
- (A) 35-99% by weight polyamide,
- (B) 1-65% by weight graft product, and
- (C) 0-1% by weight, based on total weight of A and B, of fine particles of polytetrafluoroethylene, where B comprises,
- (B1) 65-85% by weight of a graft base, where B1 is a particulate, cross-linked diene rubber having an average particle diameter (d.sub. 50) of 0.25-0.8 .mu.m, a gel content of at least 70% by weight and a glass transition temperature of less than -20.degree. C. and
- (B2) 35-15% by weight of a graft superstrate obtained by graft polymerizing, in the presence of a latex of B1, onto B1, more than 40% by weight of a monomer mixture based on the weight of B1 and where the monomer mixture consists essentially of,
- (B2.1) 99-80 parts by weight methyl methacrylate,
- (B2.2) 1-20 parts by weight n-butyl acrylate, and
- (B2.3) 0-4 parts by weight of a urethane having acrylic acid ester or methacrylic acid ester groups in the molecule which are capable of copolymerization with B2.1 and B2.2.
5 more elements
A thermoplastic moulding material comprising,
- (A) 35-99% by weight polyamide,
- (B) 1-65% by weight graft product, and
- (C) 0-1% by weight, based on total weight of A and B, of fine particles of polytetrafluoroethylene, where B comprises,
- (B1) 65-85% by weight of a graft base, where B1 is a particulate, cross-linked diene rubber having an average particle diameter (d.sub.50) of 0.25-0.8 .mu.m, a gel content of at least 70% by weight and a glass transition temperature of less than -20.degree. C. and
- (B2) 35-15% by weight of a graft superstrate obtained by graft polymerizing, in the presence of a latex of B1, onto B1, more than 40% by weight of a monomer mixture based on the weight of B1 where the monomer mixture consists essentially of
- 98-82 parts by weight methyl methacylate,
- 2-18 parts by weight primary C.sub.2 -C.sub.20 -alkyl acrylate, 0.1-3 parts by weight of a urethane having acrylic acid ester or methacrylic acid ester groups in the molecule which are capable of copolymerization with B2.1 and B2.2, and 0.1-3 parts by weight of a tertiary acrylic acid butyl ester.
4 more elements
Dependencies are inferred from the claim text.