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US 4,785,043 AGranted
Pressure-sensitive adhesive composition produced from a base block copolymer, a resinous tackifier, a naphthenic or parffinic mineral oil, and an aromatic synthetic oil
AssigneeNippon Oil Co., Ltd.
InventorsKazuo Kawai, Saburo Matsubara
Life of this patent
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Abstract
Pressure-sensitive adhesive compositions are disclosed which essentially comprise (I) a base block copolymer, (II) a resinous tackifier, (III) a selected naphthenic or paraffinic mineral oil and (IV) a selected aromatic synthetic oil. Tackiness, adhesion, cohesion and corrugated fiber board adhesiveness characteristics can be greatly improved by the addition of specified amounts of such mineral oil and aromatic oil as softeners.
Claims4
An adhesive composition of a thermoplastic elastomer type which comprises:
- (I) 100 weight parts of a base polymer of a block copolymer or its hydrogenated derivative represented by the formula
- A--B--A).sub.n
- where A is a block polymer of a monovinyl substituted aromatic hydrocarbon, B is an elastomeric block polymer of a conjugated diene, and n is an integer of 1-5;
- (II) 50-200 weight parts of a resinous tackifier;
- (III) 5-50 weight parts of a softener which is a naphthenic or paraffinic mineral oil;
- and
- (IV) 1-40 weight parts of at least one of the following synthetic oils:
- (a) a synthetic oil having a molecular weight of 173-263 and represented by the formula
- Ar.sub.1 --R--Ar.sub.2
- where Ar.sub.1 and Ar.sub.2 are each benzene or alkyl benzene rings and may be the same or different, and R is an alkylene group of 2-3 carbon atoms;
- (b) a synthetic oil having a molecular weight of 300-398 and represented by the formula
- Ar.sub.1 --R.sub.1 --Ar.sub.2 --R.sub.2 --Ar.sub.3
- where Ar.sub.1, Ar.sub.2 and Ar.sub.3 are each benzene or alkyl benzene rings and may be the same or different, R.sub.1 and R.sub.2 are each alkylene groups of 2-3 carbon atoms and may be the same or different;
- and
- (c) a synthetic oil having a molecular weight of 300-398 and represented by the formula ##STR3## where Ar.sub.1, Ar.sub.2 and Ar.sub.3 are each benzene or alkyl benzene rings and may be the same or different, and R is a straight-chain or branched-chain hydrocarbon group of 4-6 carbon atoms,
- whereby, the composition has an adhesive force of longer than 180 minutes as determined on corrugated fiberboard at a temperature of 25.degree. C. and at a load of 2,000 g.
13 more elements
Dependencies are inferred from the claim text.