Curing composition
AssigneeImperial Chemical Industries PLC
InventorsAugust L. L. Palluel, Stephen P. Davis, Angela C. Fletcher
Life of this patent
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Abstract
A curing composition comprising a silane functional acrylic polymer component and a silane functional oligomer component. The polymer component is a co-polymer of functional silyl group-containing units derived from monomers of Formula: CH.sub.2 .dbd.CR.sup.1 CO.sub.2 (CH.sub.2).sub.a L The oligomer component is of formula E(GKL).sub.6 in which E is derived from a multifunctional isocyanate oligomer, G is of general formula: --[O(CH.sub.2).sub.5 CO].sub.C [O(CH.sub.2).sub.d OCO(CH.sub.2).sub.2 ]-- and K is of general formula: --[NR.sup.5 (CH.sub.2).sub.m ]-- and where L is a group of Formula ##STR1##
Claims9
A curing composition comprising a polymer component and a compatible oligomeric component, the polymer component being a co-polymer of functional silyl group-containing units derived from monomers of Formula (1):
- CH.sub.2 .dbd.CR.sup.1 CO.sub.2 (CH.sub.2).sub.a L Formula (I)
- where a is 2 to 6
- R.sup.1 is hydrogen or methyl and
- L is a group of Formula (II):
- ##STR7## where R.sup.2 is C.sub.1-4 alkoxy, C.sub.2-4 alkoxy--C.sub.2-4 alkoxy, C.sub.1-4 alkanoyl, enolate or oximate, and R.sup.3 and R.sup.4 are C.sub.1-4 alkoxy, C.sub.2-4 alkoxy--C.sub.2-4 alkoxy, C.sub.1-4 alkanoyl, enolate, oximate or C.sub.1-6 alkyl;
- and structural units derived from polymerisable ethylenically unsaturated monomers such that each molecule of the polymer component contains at least two silyl groups of Formula (II);
- the oligomeric component being a compound of Formula (III):
- E(GKL).sub.b Formula (III)
- where b is 3 to 6;
- E is derived from a biuret or isocyanurate oligomer of a di-functional isocyanate, the isocyanate being a C.sub.4-15 aliphatic, cycloaliphatic or aromatic diisocyanate optionally substituted with one or more C.sub.1-6 alkyl groups or is derived from an adduct of C.sub.2-6 aliphatic diol, triol or tetraol and a poly functional isocyanate, the poly functional isocyanate being either a di-functional isocyanate as previously defined or being itself the adduct of an aliphatic triol and a di-functional isocyanate as previously defined,
- G is
- --[O(CH.sub.2).sub.5 CO].sub.c [O(CH.sub.2).sub.d OCO(CH.sub.2).sub.2 ]--
- in which c is 0 to 2, d is 2 to 4;
- K is
- --[NR.sup.5 (CH.sub.2).sub.m ]--
- in which m is 1 to 6, and R.sup.5 is hydrogen, methyl, --(CH.sub.2).sub.n R.sup.6, or --CH.sub.2 CHOH(CH.sub.2).sub.n --R.sup.6 in which R.sup.6 is the group L as defined with reference to Formula (I) and n is 1 to 4.
Dependencies are inferred from the claim text.