Expandable thermoplastic resin beads
AssigneeGeneral Electric Company
InventorsRichard B. Allen, William E. Gibbs, Lynn M. Hans
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Abstract
A process for producing expandable thermoplastic resin beads which comprises suspending in an aqueous medium interpolymer beads comprising a polyphenylene ether resin and a polymerized vinyl aromatic monomer such as styrene, polymerizing the vinyl aromatic monomer in the presence of a polymerization catalyst to interpolymerize the vinyl aromatic monomer with the polyphenylene ether and, optionally, adding a cross-linking agent, to form interpolymerized thermoplastic resin beads, and introducing a blowing agent under pressure into the thermoplastic resin beads. The resulting resin beads have excellent foamability and molding fusability, and a foamed shaped article having superior thermal stability can be prepared from these beads.
Claims9
A process for producing expandable thermoplastic interpolymer resin beads which comprises suspending in an aqueous medium from 1 to 50 parts by weight of a polyphenylene ether resin and 99 to 50 parts by weight of a vinyl aromatic monomer per 100 parts by weight of resin and monomer;
- adding a polymerization catalyst and polymerizing the vinyl aromatic monomer to form interpolymerized thermoplastic resin beads and during the interpolymerization or subsequently impregnating the interpolymerized thermoplastic resin beads under pressure with an easily volatilizable hydrocarbon or halogenated hydrocarbon blowing agent.
Dependencies are inferred from the claim text.