An electrophotographic imaging member comprising a substrate, a metal base layer, a zirconium metal layer comprising at least 50 percent by weight of zirconium, a blocking layer comprising a siloxane contiguous to said zirconium metal layer, said metal base layer comprising a metal which oxidizes more slowly than zirconium during passage of an electric current, said siloxane comprising a reaction product of a hydrolyzed silane having the general formula ##STR15## wherein R.sub.1 is an alkylidene group containing 1 to 20 carbon atoms and R.sub.2 and R.sub.3 are independently selected from the group consisting of H, a lower alkyl group containing 1 to 3 carbon atoms, a phenyl group, a poly(ethylene)amino group and an ethylene diamine group, an adhesive layer comprising a film forming polymer, a charge generation layer comprising photoconductive particles dispersed in a film forming binder, and a hole transport layer comprising a solid solution of a polycarbonate resin material and a diamine compound, said diamine compound having the general formula:
- ##STR16## wherein X is selected from the group consisting of an alkyl group having from 1 to about 4 cabon atoms and chlorine.