Hydrotreating catalyst and process for its preparation
AssigneePhillips Petroleum Company
InventorsStephen L. Parrott, Lloyd E. Gardner
Life of this patent
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Abstract
A catalyst composition comprises (a) alumina, (b) zinc titanate, (c) at least one compound of molybdenum, (d) at least one compound of at least one of nickel and cobalt, and (e) at least one compound containing phosphorus and oxygen. This catalyst composition is used for hydrotreating a liquid hydrocarbon-containing feed stream (such as a heavy oil) which contains compounds of nickel, vanadium and sulfur, under such conditions as to obtain a product having reduced levels of nickel, vanadium and sulfur.
Claims13
A composition of matter useful as a hydrotreating catalyst composition, comprising:
- (a) alumina,
- (b) zinc titanate,
- (c) at least one compound of molybdenum,
- (d) at least one compound of nickel, and
- (e) at least one compound containing phosphorus and oxygen.
A process for preparing a composition of matter, useful as a hydrotreating catalyst composition, comprising
- (a) alumina,
- (b) zinc titanate,
- (c) at least one compound of molybdenum,
- (d) at least one compound of nickel, and
- (e) at least one compound containing phosphorus and oxygen, said process comprising the steps of:
- (i) mixing alumina and zinc titanate;
- (ii) impregnating the mixture of alumina and zinc titanate obtained in step (i) with an aqueous solution containing at least one compound of Mo, at least one compound of Ni, and at least one compound containing P and O;
- (iii) drying the thus impregnated mixture obtained in step (ii);
- and
- (iv) calcining the dried mixture obtained in step (iii) under such conditions and at a temperature high enough to at least partially convert said at least one compound of Mo used in step (ii) to at least one oxide of Mo, and said at least one compound of Ni used in step (ii) to at least one compound selected from the group consisting of oxide of Ni and phosphate of Ni.
Dependencies are inferred from the claim text.