US 4,754,094 A · Fixed bed reactor system

Abstract

A method is disclosed in which a first gas is contacted with a solid at an elevated reaction temperature to produce a gaseous product, the solid being deactivated during said contact and exothermically reactivated by a second gas and again contacted with the first gas, the improvement includes the steps of: (a) providing a quantity of the solids in relatively equal amounts to at least these fixed bed reactors; (b) sequentially operating each fixed bed reactor according to the cycle comprising: (1) preheating introducing the first gas into a first end of the reactor and withdrawing gaseous product from a second end of the reactor; (2) preheating the first gas to reaction temperature by introducing the first gas into the fixed bed of solids at a plurality of points along the length of the reactor and withdrawing the preheated gas from the second end of the reactor; and (3) reactivating the deactivated solids by introducing the second gas into the fixed bed of solids at a plurality of points along the length of the reactor and withdrawing second gas effluent from the first end of the reactor; and (c) concurrently operating the reactors such that, at any given time, the first gas is being preheated to reaction temperature in at least one reactor, and the preheated first gas is being converted into second gas in at least one second reactor.

Claims10

Dependent claims

In a chemical conversion process wherein a gaseous reactant is contacted with a solid at an elevated reaction temperature to produce a gaseous reaction product, said solid being deactivated during said contact, and said deactivated solid being reactivated by contact with a reactivating gas under exothermic conditions and again contacted with said gaseous reactant, the improvement which comprises:

(a) providing a quantity of solids in relatively equal amounts in at least three fixed bed reactors,
(b) sequentially operating each fixed bed reactor according to the cycle comprising:
(1) introducing said gaseous reactant, preheated to reaction temperature, into a first end of said reactor and withdrawing gaseous reaction product from a second end of the reactor;
(2) preheating said gaseous reactant to reaction temperature by introducing said reactant into said fixed bed of solids at a plurality of points along the length of said reactor and withdrawing preheated gas from a second end of the reactor;
and (3) reactivating deactivated solids by introducing said reactivating gas into said fixed bed of solids at a plurality of points along the length of said reactor and withdrawing gaseous effluent from a first end of the reactor;
and
(c) concurrently operating said reactors such that, at any given time, the gaseous reactant is being preheated to reaction temperature in at least one reactor, and said preheated gaseous reactant is being converted into said gaseous reaction product in at least one second reactor.

4 more elements

In a method for converting methane to higher hydrocarbon products wherein a gas comprising methane is contacted at a reaction temperature within the range of about 500.degree. to 1000.degree. C. with a quantity of solids comprising at least one reducible oxide of at least one metal which oxides are reduced when contacted with methane and produce higher hydrocarbon products and water and wherein solids comprising reduced metal oxide(s) are periodically contacted with an oxygen-containing gas to regenerate solids comprising said reducible oxide(s), the improvement which comprises:

(a) providing the quantity of solids in relatively equal amounts in at least three fixed bed reactors;
(b) sequentially operating each fixed bed reactor according to the cycle comprising:
(1) introducing a gas comprising methane, preheated to reaction temperature, into a first end of said reactor and withdrawing gaseous reaction products comprising higher hydrocarbons from a second end of the reactor;
(2) preheating said gas comprising methane to reaction temperature by introducing said gas into said fixed bed of solids at a plurality of points along the length of said reactor and withdrawing preheated gas comprising methane from a second end of the reactor;
and (3) regenerating solids comprising reducible metal oxides by introducing an oxygen-containing gas into said fixed bed of solids at a plurality of points along the length of said reactor and withdrawing gasesous effluent from a first end of the reactor;
and
(c) concurrently operating said reactor such that at any give time, the gas comprising methane is being preheated to reaction temperature in at least one first reactor, and said preheated gas comprising methane is being converted into hydrocarbon products in at least one second reactor.

4 more elements

(a) providing the quantity of solids in relatively equal amounts in at least one module consisting of four fixed beds of solids;
(b) sequentially operating each bed of each said module according to the following cycle:
(1) introducing a gas comprising methane, preheated to reaction temperature, into a first end of the bed and withdrawing gaseous reaction product comprising higher hydrocarbons from a second end of the bed;
(2) preheating a gas comprising methane to reaction temperature by introducing said gas into the bed at a plurality of points along the length of the bed and withdrawing preheated gas from a second end of the bed, thereby cooling the solids;
(3) purging the gas comprising methane from the cooled solids;
(4) regenerating solids comprising reducible metal oxide(s) by introducing an oxygen-containing gas into the cooled, purged solids at a plurality of points along the length of the bed and withdrawing gaseous effluent from a first end of the bed;
and (5) purging the oxygen-containing gas from the regenerated solids;
and
(c) concurrently operating the beds of said module such that, at any given time, a gas comprising methane is being preheated to reaction temperature in one first bed, said preheated gas is reacting to form higher hydrocarbon products in one second bed, solids comprising reducible metal oxides(s) are being regenerated in one third bed, and one fourth bed is being purged.

6 more elements

In a method for dehydrogenating dehydrogenatable hydrocarbons wherein a gas comprising said hydrocarbon is contacted at a reaction temperature within the range of about 500.degree. to 1000.degree. C. with a quantity of solids comprising at least one reducible oxide of at least one metal which oxides are reduced when contacted with hydrocarbon and produce dehydrogenated hydrocarbon products and water and wherein solids comprising reduced metal oxide(s) are periodically contacted with an oxygen-containing gas to regenerate solids comprising said reducible oxide(s), the improvement which comprises:

(a) providing the quantity of solids in relatively equal amounts in at least three fixed bed reactors;
(b) sequentially operating each fixed bed reactor according to the cycle comprising:
(1) introducing a gas comprising said hydrocarbon preheated to reaction temperature, into a first end of said reactor and withdrawing gaseous reaction products comprising dehydrogenated hydrocarbons from a second end of the reactor;
(2) preheating said gas comprising hydrocarbon to reaction temperature by introducing said gas into said fixed bed at a plurality of points along the length of said reactor and withdrawing preheated gas comprising dehydrogenatable hydrocarbons from a second end of the reactor;
and (3) regenerating solids comprising reducible metal oxides by introducing an oxygen-containing gas into said fixed bed of solids at a plurality of points along the length of said reactor and withdrawing gaseous effluent from a first end of the reactor;
and
(c) concurrently operating said reactors such that at any given time, the gas comprising said hydrocarbon is being preheated to reaction temperature in at least one first reactor, and said preheated gas is being converted into dehydrogenated hydrocarbon products in at least one second reactor.

4 more elements

Dependencies are inferred from the claim text.

Fixed bed reactor system

Life of this patent

Fixed bed reactor system

Life of this patent

Abstract

Claims10