Substituted diphenyl ethers, herbicides containing these compounds and their use as herbicides
AssigneeBASF SE
InventorsAdolf Parg, Bruno Wuerzer, Gerhard Hamprecht
Life of this patent
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AssigneeBASF SE
InventorsAdolf Parg, Bruno Wuerzer, Gerhard Hamprecht
Estimating the term…
Substituted diphenyl ethers of the formula ##STR1## where Z.sub.1, Z.sub.2 and Z.sub.3 are hydrogen, halogen, nitro, cyano, carboxyl, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylmercapto, haloalkylmercapto, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl or haloalkylsulfonyl, Z.sub.4 is hydrogen, cyano, alkyl, alkoxy, acetoxy or alkylmercapto, Y is hydrogen, halogen, cyano or nitro, X is oxygen, sulfur, sulfinyl or sulfonyl, and A is hydrogen, unsubstituted or substituted alkyl ##STR2## and can also be sulfonyl ##STR3## when X is oxygen, and, when Z.sub.4 is alkoxy or alkylmercapto, can also be a methylene chain --(CH.sub.2).sub.m -- by which the radicals Z.sub.4 --CH--X-- are bonded to form a ring, R.sub.1 is hydrogen, methyl, ethyl or n-propyl, R.sub.2 is cyano, methoxy, ethoxy or ##STR4## where B is OH, ONa, O--alkyl, unsubstituted or substituted phenoxy, --NH.sub.2, --NH--alkyl or --N(alkyl).sub.2, n is 1, 2 or 3, R.sub.3 and R.sub.4 are hydrogen, halogen, methyl, nitro, cyano, methoxy, carboxyl, trifluoromethyl or an O-propionic acid methyl ester group, R.sub.5 is methyl, ethyl, propyl, chloromethyl, dichloromethyl, trichloromethyl, methoxymethyl, phenyl, nitro-substituted phenyl, alkyl-substituted phenyl or .alpha.-2,4-dichlorophenoxyethyl, R.sub.6 and R.sub.7 are hydrogen, alkyl, alkoxyalkyl, dihalophenyl, cyclohexyl or methoxy, R.sub.8, R.sub.9 and R.sub.10 are methyl, ethyl, n-propyl or n-butyl, R.sub.11 and R.sub.12 are methoxy, ethoxy, thiomethyl, thioethyl, thio-n-propyl, N,N-dimethylamino or N,N-diethylamino, R.sub.13 is methyl, ethyl, phenyl or trifluoromethyl, R.sub.14 and R.sub.15 are hydrogen, methyl, ethyl, n-propyl, isopropyl, n-butyl, n-hexyl, n-heptyl, methoxy, ethoxy or isopropoxy, and m is 2 or 3; and herbicides containing these compounds.
A substituted diphenyl ether of the formula ##STR102## where Z.sub.1 is 2-chloro, Z.sub.2 is 4-trifluoromethyl, Z.sub.3 is hydrogen, Z.sub.4 is hydrogen, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, acetoxy or C.sub.1 -C.sub.4 -alkylmercapto, Y is chlorine, bromine, cyano or nitro, X is oxygen, sulfur, sulfinyl or sulfonyl, and A is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 alkyl substituted by tetrahydrofuryl;
A substituted diphenyl ether selected from the group consisting of methyl 3-(2'-chloro-4'-trifluoromethylphenoxy)-benzylthioacetate, methyl 3-(2'-chloro-4'-trifluoromethylphenoxy)-6-nitrobenzoxyacetate, methyl 3-(2'-chloro-4'-trifluoromethylphenoxy)-6-nitrobenzylthioacetate, methyl 3-(2'-chloro-4'-trifluoromethylphenoxy)-6-bromobenzylthioacetate, ##STR110##
A compound represented by the formula:
Dependencies are inferred from the claim text.