Bismuth/carboxylic acid catalysts for preparing elastomers
AssigneeThe Dow Chemical Company
InventorsDouglas L. Hunter, David E. Schiff
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AssigneeThe Dow Chemical Company
InventorsDouglas L. Hunter, David E. Schiff
Estimating the term…
This invention is a polyurethane-urea elastomer which is the reaction product of a reaction mixture comprising (1) a liquid active hydrogen-containing composition which comprises a relatively high equivalent weight active hydrogen-containing compound, and an amine-terminated, relatively low equivalent weight compound, (2) a polyisocyanate which is present in an amount to provide about 0.8 to about 1.5 isocyanate groups per active hydrogen-containing group present in the mixture, and (3) a catalytically effective amount of a bismuth carboxylate catalyst. With the use of the bismuth carboxylate catalyst, excellent pot-life, yet rapid cures are achieved. In addition the so-called "green strength" of the elastomer, i.e., its physical strength at the time of its removal from the mold, is improved with the practice of this invention. Further, the post-cured elastomer exhibits excellent properties.
A polyurethane-urea elastomer which is the reaction product of a reaction mixture comprising (1) a liquid active hydrogen-containing composition which comprises a relatively high equivalent weight active hydrogen-containing compound, and an amine-terminated, relatively low equivalent weight compound, (2) a polyisocyanate which is present in an amount to provide about 0.8 to about 1.50 isocyanate groups per active hydrogen-containing group present in the mixture, and (3) a catalytically effective amount of a bismuth carboxylate catalyst.
A liquid active hydrogen-containing composition comprising (a) a relatively high equivalent weight polyol, (b) an aromatic amine chain extender and (c) a catalytically effective amount of a bismuth carboxylate.
A process for forming a polyurethane-urea elastomer by reacting a reaction mixture comprising (1) a liquid active hydrogen-containing composition which comprises a relatively high equivalent weight active hydrogen-containing comound, and an amine-terminated, relatively low equivalent weight compound, having at least two primary or secondary groups per molecule, (2) a polyisocyanate which is present in an amount to provide about 0.8 to about 1.50 isocyanate groups per active hydrogen-containing group present in the mixture, and (3) a catalytically effective amount of a bismuth carboxylate catalyst.
Dependencies are inferred from the claim text.