US 4,741,770 AGranted

Zinc smelting process using oxidation zone and reduction zone

AssigneeCRA Services Limited

InventorsBarry S. Andrews, James D. Iley, Mark I. Hoschke, Gregorey J. Hardie, Michael J. Hollitt

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Abstract

A smelting process of superior energy efficiency, particularly suitable for the extraction of zinc, but also of lead and copper from raw materials comprising sulphide concentrates, and oxidized metalliferous materials, is carried out by establishing at least one oxidation zone and at least one reduction zone in a furnace, each zone comprising a slag bath and a gas space; the gas spaces of the oxidation and reduction zones being separated by a partition; feeding raw materials comprising metal sulphides, together with fluxes, to the or each oxidation zone, and feeding oxygen or oxygen-rich gas into the slag bath in the or each oxidation zone to oxidize metal compounds therein and produce an off-gas containing SO.sub.2 ; transferring metal-oxide-bearing slag from at least one oxidation zone to at least one reduction zone; introducing coal into the or each reduction zone to reduce metal oxides therein, and produce gases containing carbon monoxide and hydrogen; introducing a controlled stream of oxygen into the or each reduction zone, the amount of oxygen in the said stream being sufficient to partly post-combust carbon monoxide and hydrogen, thereby producing heat which is transferred back to the slag bath in the reduction zone, while leaving the gases sufficiently reduced to ensure that reduced metal is not re-oxidized; and recovering reduced metal from at least one reduction zone.

A zinc smelting process which comprises

(a) establishing at least one oxidation zone and at least one reduction zone in a furnace each zone comprising a slag bath and a gas space;
the gas spaces of the oxidation and reduction zones being separated by a partition;
(b) maintaining a molten matte phase rich in cuprous sulphide in the or each oxidation zone, feeding raw materials comprising zinc sulphides and iron sulphides, together with fluxes, to the or each oxidation zone, and feeding oxygen or oxygen-rich gas into the molten bath in the or each oxidation zone to oxidise metal compounds therein to produce a slag bearing zinc oxide and iron oxide and to produce an off-gas containing fume and SO.sub.2, said fume containing zinc and other volatiles;
(b.1) removing from said oxidation zone the off-gas produced in stp (b), removing fume from said off-gas, separating volatiles other than zinc from the removed fume to produce a zinc-containing fume residue, and recycling said zinc-containing fume residue to the oxidation zone;
(c) transferring zinc oxide-bearing slag from at least one oxidation zone to at least one reduction zone;
(d) introducing coal into the or each reduction zone to reduce zinc oxide present in said zinc oxide-bearing slag to produce reduced zinc, discard slag, and reducing gases containing carbon monoxide and hydrogen, said discard slag containing iron oxide;
(e) introducing a controlled stream of oxygen into the or each reduction zone, the amount of oxygen in the said stream being sufficient to partly post-combust said carbon monoxide and hydrogen, thereby producing heat which is transferred back to the slag bath in the reduction zone, while leaving said reducing gases sufficiently reducing to ensure that zinc vapor is not re-oxidised;
(f) recovering reduced zinc from at least one reduction zone;
and
(g) removing discard slag from at least one reduction zone, dividing the removed discard slag into two streams, passing one of the streams to waste, passing the other stream to an iron reduction reactor to reduce iron oxide present in said discard slag to produce iron metal, off-gases, and a low-iron slag, recycling iron metal to the zinc reduction zone, and recycling low-iron slag from the reduction reactor to the oxidation zone.

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Abstract

Claims4