Process for passivating high activity transition metal sulfide catalysts
AssigneeGas Research Institute
InventorsHenry Wise, Benny L. Chan
Life of this patent
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Abstract
Catalysts having as their active component sulfides of vanadium, molybdenum and tungsten are contacted with ammonia or with an amine which in aqueous solution has a basic ionization constant greater than that of ammonium hydroxide to suppress deactivation of the catalysts by exposure to the atmosphere.
Claims6
The method of passivating catalysts in which the active catalytic component is a material having the formula MS.sub.1.5-3 in which M is a metal selected from the group consisting of molybdenum, vanadium, tungsten and their mixtures by contacting the catalysts with a material selected from the group consisting of ammonia and amines the water solutions of which have a basic ionization constant greater than that of ammonium hydroxide, said contacting being made by exposing said catalysts to an atmosphere consisting of an inert gas containing at least 1% by weight of the selected material in vapor phase and maintaining the contact until adsorption of the selected material by the catalyst ceases.
The method of passivating catalysts having the empirical atomic formula
- XY.sub.x Z.sub.y S.sub.z O.sub.w C.sub.t N.sub.v
- wherein
- X is a transition element or a mixture thereof selected from the group V, Mo, W
- Y is a support element or a mixture thereof selected from the group Al, Si, B, Ce, Ti, Zr, where x can vary from 0 to 1
- Z is a promoter element or mixture thereof selected from the group Co, Ni, Fe, Mn, where y can vary from 0 to 0.1
- S is the element sulfur, where z can vary from 1.3 to 3
- O is the element oxygen, where w can vary from 0 to the upper limit required by the stoichiometry
- C is the element carbon, where t can vary from 0 to 0.1
- N is the element nitrogen, where v can vary from 0 to 0.1,
- and which undergo substantial and rapid deactivation when exposed to the atmosphere by contacting said catalysts with a material selected from the group consisting of ammonia and amines which in aqueous solution have a basic ionization constant greater than that of ammonium hydroxide, said contacting being made by exposing said catalysts to an atmosphere consisting of an inert gas containing at least 1% by weight of the selected material in vapor phase for a time sufficient to substantially prevent reaction with oxygen and/or water vapor with the catalyst when it is exposed to the atmosphere.
The method of treating a granular catalyst in which the active catalytic material is a pyrophoric compound having the formula MS.sub.1.5-3 in which M is a metal selected from the group consisting of molybdenum, vanadium, tungsten and their mixtures to render the active catalytic material non-pyrophoric when it is exposed to the atmosphere, which comprises exposing the catalyst to an atmosphere consisting of an inert gas containing at least 1% by weight of an amine having a basic ionization constant greater than 5.times.10.sup.-4 and continuing the exposure until adsorption of the amine substantially ceases.
Dependencies are inferred from the claim text.