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US 4,739,042 AGranted
Halftone gravure printing inks containing pyridone azo dyestuffs
AssigneeBayer Aktiengesellschaft
InventorsManfred Lorenz, Artur Haus
Life of this patent
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Abstract
Halftone gravure printing inks containing pyridone azo dyestuffs wherein the dyestuffs are obtained by reacting a pyridone dyestuff of the formula ##STR1## with a dicarboxylic or polycarboxylic acid or a pyridone azo dyestuff of the formula ##STR2## with a dihydroxy or polyhydroxy compound.
Claims3
A dyestuff which is obtained by reacting a pyridone azo dyestuffs of the formula ##STR52## in which D denotes the radical of a diazo component,
- T.sub.1 denotes alkyl, aryl or --COOT.sub.4,
- T.sub.2 denotes H, --CN, --COOT.sub.4 or --CONH--T.sub.5 (OH).sub.n,
- T.sub.4 denotes hydrogen or alkyl,
- if n is 0, T.sub.3 and T.sub.5 each independently represent C.sub.1 -C.sub.22 -alkyl, C.sub.2 -C.sub.22 -alkenyl, C.sub.3 -C.sub.7 -cycloalkyl, benzyl, phenethyl, C.sub.2 -C.sub.18 -alkoxyalkyl, phenoxy-C.sub.1 -C.sub.22 -alkyl or phenoxy-C.sub.2 -C.sub.18 -alkoxy? alkyl and if n is 1, 2, 3 or 4,T.sub.3 and T.sub.5 each independently represent a C.sub.2 -C.sub.18 -alkyl or C.sub.2 -C.sub.18 -alkyl which is interrupted by 1-6 oxygen atoms and
- m and n denote 0, 1, 2, 3 or 4, subject to the proviso that the sum of m+n is 1, 2, 3 or 4, with oxalic acid or a carboxylic acid of the formula
- [G']-(COOH).sub.a
- in which G' denotes an aliphatic or aromatic hydrocarbon radical having 1-51 carbon atoms and a denotes 2, 3 or 4 or a carboxylic acid of the formula
- [G"]-(OCH.sub.2 CH.sub.2 -COOH).sub.a '
- in which G" denotes a saturated or unsaturated hydrocarbon radical having 2 to 20 carbon atoms or a saturated or unsaturated hydrocarbon radical in which the carbon chain can be interrupted by 1-9 non-adjacent oxygen atoms and a' denotes 2, 3, 4 or 5 to form an ester linkage between at least two identical or different pyridone azo dyestuffs.
6 more elements
A dyestuff of the formula
- [P.sub.y1 ]--N.dbd.N--L'-N.dbd.N-[P.sub.y2 ]
- in which [P.sub.y1 ] and [P.sub.y2 ] denote pyridone radicals which, in one of their tautomeric forms, correspond to the formulae ##STR54## in which T.sub.1 denotes alkyl, aryl or --COOT.sub.4,
- T.sub.2 denotes H, --CN, --COOT.sub.4, or --CONH--T.sub.5 (OH).sub.n,
- if n is 0, T.sub.3 and T.sub.5 each independently reprsents C.sub.1 -C.sub.22 -alkyl, C.sub.2 -C.sub.22 -alkenyl, C.sub.3 -C.sub.7 -cycloalkyl, benzyl, phenethyl, C.sub.2 -C.sub.18 -alkoxyalkyl, phenoxy-C.sub.1 -C.sub.22 -alkyl or phenoxy-C.sub.2 -C.sub.18 -alkoxy-alkyl, if n is 1,2,3 or 4, T.sub.3 represents a C.sub.2 -C.sub.18 -alkyl or C.sub.2 -C.sub.18 -alkyl which is intrrupted by 1-6 oxygen atoms,
- T.sub.2 ' denotes H, --CN or --COOT.sub.4
- T.sub.4 denotes hydrogen or alkyl,
- if n is 0, T.sub.9 represents C.sub.1 -C.sub.22 -alkyl, C.sub.2 -C.sub.22 -alkenyl, C.sub.3 -C.sub.7 -cycloalkyl, benzyl, phenethyl, C.sub.2 -C.sub.18 -alkoxyalkyl, phenoxy-C.sub.1 -C.sub.22 -alkyl or phenoxy-C.sub.2 -C.sub.18 -alkoxyalkyl,
- if n is 1, 2, 3 or 4, T.sub.9 represents a C.sub.1 -C.sub.12 -alkyl,
- n denotes 0,1,2,3 or 4 and
- L' rrepresents ##STR55## wherein the cyclopentylene and cyclohexylene radicals are unsubstituted or are substituted C.sub.1 -C.sub.4 -alkyl, and the phenylene radical is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, --NO.sub.2 and Cl.
7 more elements
Dependencies are inferred from the claim text.