Surfactants from lignin
AssigneeTexaco Inc.
InventorsDouglas G. Naae, Lawrence E. Whittington, Will A. Ledoux, Francis E. Debons
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Abstract
A method of producing surfactants from lignin is disclosed by reducing lignin in the presence of a carbon monoxide or hydrogen reducing agent at high temperature and pressure to produce low molecular weight lignin phenols and subjecting the lignin phenols to one or a combination of several reactions such as alkoxylation, alkylation, sulfonation, sulfation, alkoxysulfation, and sulfomethylation. The lignin surfactants so produced can be employed in a surfactant system to recover oil from underground formations.
Claims42
A method of producing surfactants from lignin, which comprises:
- placing lignin in contact with water;
- converting the lignin into low molecular weight-lignin phenols by reducing the lignin in the presence of a reducing agent of carbon monoxide or hydrogen,
- said reduction occurring at a temperature greater than about 200.degree. C. and a pressure greater than about 100 psi;
- recovering the oil soluble lignin phenols from the reaction mixture;
- converting the lignin phenols into lignin surfactants by a reaction selected from the group consisting of alkoxylation, sulfonation, sulfation, alkylation, sulfomethylation, and alkoxysulfation.
Dependencies are inferred from the claim text.