Cyclic polycarbonate oligomers from spirobiindane bisphenols
AssigneeGeneral Electric Company
InventorsDaniel J. Brunelle, Thomas L. Evans, Thomas G. Shannon
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Abstract
Cyclic polycarbonate mixtures containing units derived from spirobiindane bisphenols, preferably 6,6'-dihydroxy-3,3,3',3'-tetramethylspirobiindane, are prepared from the corresponding bischloroformates or mixtures thereof with bisphenols. They may be homopolymeric or copolymeric; cyclic oligomer mixtures are preferred. Such oligomers may be converted to linear polycarbonates having high glass transition temperatures.
Claims9
A composition comprising cyclic oligomers containing spirobiindane structural units of the formula ##STR7## wherein each R.sup.1 is independently C.sub.1-4 primary or secondary alkyl or halo and n is from 0 to 3.
Dependencies are inferred from the claim text.