Aqueous coating composition based on a cationic binder
AssigneeAkzo N.V.
InventorsChantal H. Guioth, Etienne G. Maze, Loick P. Rabajoie
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Abstract
A process is provided for coating an electrically conductive substrate with an aqueous composition containing a cationic binder wherein the binder is obtained by polymerization of 100 parts by weight of a specified monomer mixture in the presence of 0.25 to 4 parts by weight of an acrylic or methacrylic bisphenol ester. The invention also pertains to the aqueous composition as such.
Claims14
An aqueous coating composition based on a cationic binder obtained by polymerization of a monomer mixture in the presence of 0.25-4 parts by weight of a polyethylenically unsaturated compound per 100 parts by weight of the monomer mixture,
- said monomer mixture consisting of (a) 1-30% by weight of a hydroxy(cyclo)alkyl (meth)acrylate of which the (cyclo)alkyl group has 2-8 carbon atoms, (b) 4-45% by weight of an amino (meth)acrylate of the formula:
- ##STR3## wherein at least one of the groups R.sub.1 is a hydrocarbon group containing 1-12 carbon atoms and the other group R.sub.1 is a hydrocarbon group having 1-12 carbon atoms or a hydrogen atom, or the two groups R.sub.1, together with the nitrogen atom attached thereto, form a heterocyclic group, R.sub.2 is a hydrocarbon group containing 2-12 carbon atoms and R.sub.3 is a hydrogen atom or a methyl group, (c) 0-80% by weight of a monovinyl aromatic hydrocarbon containing 8-14 carbon atoms, and (d) 0-50% by weight of a different monoethylenically unsaturated monomer containing 2-20 carbon atoms;
- said polyethylenically unsaturated compound being an acrylic or methacrylic bisphenol ester of the formula
- H.sub.2 C.dbd.CHR--C(O)--(O--B).sub.m --[--O--D--A--D--(O--B).sub.m --].sub.n --O--C(O)--CHR.dbd.CH.sub.2
- wherein R represents a hydrogen atom or a methyl group, A represents a hydrocarbon group containing 1-4 carbon atoms, B represents a hydrocarbon group containing 2 or 3 carbon atoms or a 2-hydroxypropylene group and D represents a phenylene group or a cyclohexylene group, m is a number from 1-4 and n is a number from 1-3, said ester being present in an amount of 0.25-4 parts by weight per 100 parts by weight of the monomer mixture;
- amino groups present in said binder being at least partially neutralized with an acid.
A coating composition according to claim 1, wherein the bisphenol ester is a compound of the formula according to claim 17, wherein R represents a methyl group, B represents an ethylene group or a propylene group, A represents an isopropylidene group and D represents a p-phenylene group, and m and n are equal to 1.
A composition according to claim 1, wherein the bisphenol ester is a compound of the formula according to claim 17, wherein R represents a hydrogen atom or a methyl group, B represents a 2-hydroxypropylene group, D represents a p-phenylene group and A represents an isopropylidene group, and m is equal to 1 and n is equal to 3.
Dependencies are inferred from the claim text.