Process for the preparation of high absorptive sodium tripolyphosphate hexahydrate

A process for the preparation of sodium tripolyphosphate hexahydrate having high adsorption characteristics and having a pore volume of at least 0.70 cm.sup.3 /gram comprising the following steps:

• (i) spraying water or an aqueous medium over a first fraction of anhydrous sodium tripolyphosphate wherein at least 55% of the first fraction of anhydrous sodium tripolyphosphate is comprised of phase 1 tripolyphosphate;
• (ii) separately spraying water on aqueous medium over a second fraction of anhydrous sodium tripolyphosphate wherein the second fraction of anhydrous sodium tripolyphosphate consists essentially of phase 2 tripolyphosphate, and said second fraction contains not more than 10% of phase 1 tripolyphosphate and has been purified of calcium and magnesium values, and wherein the spraying operations of steps (i) and (ii) create seeds of hexahydrates so that the first and second fractions remains in essentially anhydrous form and the seeds are sufficient to promote the formation of hexahydrates of sodium tripolyphosphate, wherein such seeds are formed with water sprayed in a percentage of from 0.1 to 3% by weight based on the anhydrous sodium tripolyphosphate or with a suspension of sodium tripolyphosphate, as said aqueous medium, sprayed in a percentage of from 0.2 to 3% by weight relative to anhydrous sodium tripolyphosphate,
• (iii) intimately admixing said first and said second sprayed fractions, said intimate admixture comprising from 40 to 60% of phase 1 tripolyphosphate;
• (iv) suspending the resulting admixture in water or an aqueous medium, and thence;
• (v) drying the resulting suspension by atomization to produce hexahydrated sodium tripolyphosphate.