Process for the production of a continuous composite ribbon including an acrylate resin film to be used in safety laminated glass panels

A method of producing safety glass, comprising the steps of:

• polymerizing in the form of a continuous ribbon, a mixture of polymerizable monomers including:
• (A) one part by weight of a composition of polymerizable monomers including 60 to 97 parts by weight acrylic or methacrylic ester, 0 to 2 parts by weight acrylic or methacrylic acid, 0 to 5 parts by weight N-2-vinylpyrrolidone, 0 to 5 parts by weight acrylic or methacrylic acid ester including glycidyl groups;
• (B) 0.16 to 1.2 parts by weight of a plasticizer selected from the class consisting of adipic acid, isophthalic acid, phthalic acid, sebacic acid, epoxy derivatives and polyester derivatives;
• and
• (C) an effective amount of a catalyst of the azo or peroxy series, between a pair of transparent films of plastic material inert to said polymerizing and transparent to infrared and visible ultraviolet light by exposing said polymerizable mixture between said films to a first irradiation with light in the infrared and visible ultraviolet spectrum range and then subsequently exposing said polymerizable mixture between said films to a second irradiation with light in the infrared spectrum range absent light in said visible ultraviolet range, the amount of visible ultraviolet irradiation to which said polymerizable mixture is exposed being no more than about 10% of the total irradiation, the mixture of polymerizable monomers being irradiated for a total of 45 minutes to 3 hours, so as to form a covered elastomeric polymerized resin sheet;
• removing both of said films from said covered elastomeric polymerized resin sheet to form an uncovered elastomeric polymerized resin sheet;
• bonding said uncovered elastomeric polymerized resin between two sheets of glass adjacent top and bottom surfaces of said uncovered polymerized resin sheet to form a safety glass.