A method of manufacturing an optical fibre, characterized in that a curable synthetic resin composition which comprises one or more oligomeric compounds the molecules of which comprise reactive groups and the molecular weight of which is smaller than 5000, is applied to a glass fibre having at least one enveloping layer of synthetic rubber, in which the molecules of the curable synthetic resin composition are oriented during application to the glass fibre, after which the curable synthetic resin composition is made to cure while forming a synthetic resin the molecules of which are oriented substantially in the longitudinal direction of the optical fibre.