Oxidation resistant carbon containing alumina-silica articles
AssigneeMinnesota Mining and Manufacturing Company
InventorsGeorge F. Everitt, Terence P. Johnson, Lien-Huong T. Pham
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Abstract
A shaped article comprises a continuous alumina-silica first phase, an in-situ generated discontinuous carbon second phase, and optionally a discontinuous silicon carbide third phase, said article being stable to an oxidative atmosphere when heated to 1300.degree. C. for at least 30 minutes.
Claims24
A shaped article comprising a continuous alumina-silica or alumina-boria-silica matrix first phase and an in-situ generated discontinuous carbon second phase, said article being stable to an oxidative atmosphere when heated at 1300.degree. C. for at least 30 minutes.
A shaped article comprising a continuous alumina-silica first phase, said first phase comprising 80 to 99 weight percent of the total composition of a mixture or chemical combination of 65 to 80 weight percent alumina and 20 to 35 weight percent silica, and an in-situ generated discontinuous carbon second phase, said carbon second phase comprising 1 to 20 weight percent of the total composition, and said article being stable to an oxidative atmosphere when heated at 1300.degree. C. for at least 30 minutes.
A shaped article comprising a continuous alumina-boria-silica first phase, an in situ generated discontinuous carbon second phase, and a mechanically added discontinuous silicon carbide third phase, said first phase comprising 65 to 84 percent of a mixture of 60 to 65 weight percent alumina, 25 to 35 weight percent silica, and 0.25 to 15 parts by weight boria, said second phase comprising 1 to 5 weight percent carbon, and said third phase comprising 5 to 30 weight percent silicon carbide, said article being stable to an oxidative atmosphere when heated at 1300.degree. C. for at least 2 hours.
A process for preparing a non-refractory shaped green article comprising the steps:
- (a) providing a aqueous viscous concentrate which is capable of providing said green article comprising 55 to 99 weight percent of the total composition of a mixture or chemical combination of
- (1) 65 to 80 weight percent alumina, and
- (2) 35 to 20 weight percent silica which is derived from 70 to 99.5 weight percent of an organosilane and 25 to 0.5 weight percent amorphous silica, and
- (3) more than zero and up to 30 weight percent mechanically added silicon carbide,
- (b) shaping said viscous concentrate into a shaped form,
- (c) dehydratively or evaporatively gelling or hydrolyzing said shaped form to provide a green shaped article, and
- (d) drying said green shaped article to provide a non-refractory shaped green article.
Dependencies are inferred from the claim text.