Magnetic recording medium
AssigneeMinnesota Mining and Manufacturing Company
InventorsStephen R. Ebner, Gene A. Sjerven, Arthur J. Ellsworth, Takashi Amano, Nobuyoshi Kawasaki
Life of this patent
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Abstract
A magnetic medium consisting essentially of a cured compound derived from a low-molecular weight, phosphorylated, polyoxyalkyl polyol and an organic isocyanate compound. The binder may also include a vinyl polymer and/or a polyoxyalkyl polyol.
Claims26
A magnetic recording medium comprising a non-magnetic support and a coating of a dispersion of a magnetic powder in a binder, said binder consisting essentially of a cured compound derived from:
- (1) a phosphorylated polyoxyalkyl polyol present in an amount in the range of 30 to 80 percent by weight of the binder and represented by the following formula:
- ##STR6## wherein n.sub.1, n.sub.2 and n.sub.3 may independently be 0 to 10 inclusive and n.sub.4 is 0 or 1
- R.sub.1, R.sub.2, R.sub.3 are independently selected from the group consisting of ##STR7## R.sub.4 is selected from the group consisting of H, --CH.sub.3, --CH.sub.2 --CH.sub.3, --CH.sub.2 --CH.sub.2 --CH.sub.3, ##STR8## X is a dispersing group such as ##STR9## wherein Y.sub.1 and Y.sub.2 are selected from the group consisting of H, Na, Li, K;
- and
- (2) An organic isocyanate compound;
- wherein said phoshorylated polyoxyalkyl polyol and said organic isocyanate compound are present in a ratio which effectively homogeneously disperses said magnetic powder and securely binds said magnetic powder when coated on said non-magnetic support.
A magnetic recording medium comprising a non-magnetic support and a coating of a dispersion of a magnetic powder in a binder, said binder consisting essentially of a cured compound derived from:
- (1) a phosphorylated polyoxyalkyl polyol present in an amount in the range of 10 to 60 percent by weight of the binder and represented by the following formula:
- ##STR10## wherein n.sub.1, n.sub.2 and n.sub.3 may independently be 0 to 10 inclusive and n.sub.4 is 0 or 1
- R.sub.1, R.sub.2, R.sub.3 are independently selected from the group consisting of ##STR11## R.sub.4 is selected from the group consisting of H, --CH.sub.3, --CH.sub.2 --CH.sub.3, --CH.sub.2 --CH.sub.2 --CH.sub.3, ##STR12## X is a dispersing group such as ##STR13## wherein Y.sub.1 and Y.sub.2 are selected from the group consisting of H, Na, Li, K;
- (2) a polyoxyalkyl polyol represented by the following formula:
- ##STR14## wherein Z is --OH;
- and (3) an organic isocyanate compound,
- wherein said phosphorylated polyoxyalkyl polyol, said polyoxyalkyl polyol, and said isocyanate compound are present in a ratio which effectively homogeneously disperses said magnetic powder and securely binds said magnetic powder when coated on said non-magnetic support.
A magnetic recording medium comprising a non-magnetic support and a coating of a dispersion of a magnetic powder in a binder, said binder consisting essentially of a cured compound derived from:
- (1) a phosphorylated polyoxyalkyl polyol present in an amount in the range of 5 to 60 percent by weight of the binder and represented by the following formula:
- ##STR15## wherein n.sub.1, n.sub.2 and n.sub.3 may independently be 0 to 10 inclusive and n.sub.4 is 0 or 1
- R.sub.1, R.sub.2, R.sub.3 are independently selected from the group consisting of ##STR16## R.sub.4 is selected from the group consisting of H, --CH.sub.3, --CH.sub.2 --CH.sub.3, --CH.sub.2 --CH.sub.2 --CH.sub.3, ##STR17## X is a dispersing group such as ##STR18## wherein Y.sub.1 and Y.sub.2 are selected from the group consisting of H, Na, Li, K;
- (2) an organic isocyanate compound, and
- (3) a vinyl polymer
- wherein said phosphorylated polyoxyalkyl polyol, said isocyanate compound and said vinyl polymer are present in a ratio which effectively homogeneously disperses said magnetic powder and securely binds said magnetic powder when coated on said non-magnetic support.
A magnetic recording medium comprising a non-magnetic support and a coating of a dispersion of a magnetic powder in a binder, said binder consisting essentially of a cured compound derived from:
- (1) a phosphorylated polyoxyalkyl polyol present in an amount in the range of 5 to 60 percent by weight and represented by the following formula:
- ##STR19## wherein n.sub.1, n.sub.2 and n.sub.3 may independently be 0 to 10 inclusive and n.sub.4 is 0 or 1
- R.sub.1, R.sub.2, R.sub.3 are independently selected from the group consisting of ##STR20## R.sub.4 is selected from the group consisting of H, --CH.sub.3, --CH.sub.2 --CH.sub.3, --CH.sub.2 --CH.sub.2 --CH.sub.3, ##STR21## X is a dispersing group such as ##STR22## wherein Y.sub.1 and Y.sub.2 are selected from the group consisting of H, Na, Li, K;
- (2) a polyoxyalkyl polyol represented by the following formula:
- ##STR23## wherein Z is --OH;
- (3) an organic isocyanate compound;
- and
- (4) a vinyl polymer;
- wherein said phosphorylated polyoxyalkyl polyol, said polyoxyalkyl polyol, said isocyanate compound and said vinyl polymer are present in a ratio which effectively homogeneously disperses said magnetic powder and securely binds said magnetic powder when coated on said non-magnetic support.
A dispersion of a magnetic powder in a binder, said dispersion consisting essentially of:
- (1) a phosphorylated polyoxyalkyl polyol present in an amount in the range of 30 to 80 percent by weight of the binder and represented by the following formula:
- ##STR24## wherein n.sub.1, n.sub.2 and n.sub.3 may independently be 0 to 10 inclusive and n.sub.4 is 0 or 1
- R.sub.1, R.sub.2, R.sub.3 are independently selected from the group consisting of ##STR25## R.sub.4 is selected from the group consisting of H, --CH.sub.3, --CH.sub.2 --CH.sub.3, --CH.sub.2 --CH.sub.2 --CH.sub.3, ##STR26## X is a dispersing group such as ##STR27## wherein Y.sub.1 and Y.sub.2 are selected from the group consisting of H, Na, Li, K;
- and
- (2) an organic isocyanate compound;
- wherein said phosphorylated polyoxyalkyl polyol and said organic isocyanate compound are present in a ratio which effectively homogeneously disperses said magnetic powder and securely binds said magnetic powder when coated on said non-magnetic support.
A dispersion of a magnetic powder in a binder, said dispersion consisting essentially of:
- (1) a phosphorylated polyoxyalkyl polyol present in an amount in the range of 10 to 60 percent by weight of the binder and represented by the following formula:
- ##STR28## wherein n.sub.1, n.sub.2 and n.sub.3 may independently be 0 to 10 inclusive and n.sub.4 is 0 or 1
- R.sub.1, R.sub.2, R.sub.3 are independently selected from the group consisting of ##STR29## R.sub.4 is selected from the group consisting of H, --CH.sub.3, --CH.sub.2 --CH.sub.3, --CH.sub.2 --CH.sub.2 --CH.sub.3, ##STR30## X is a dispersing group such as ##STR31## wherein Y.sub.1 and Y.sub.2 are selected from the group consisting of H, Na, Li, K;
- (2) a polyoxyalkyl polyol represented by the following formula wherein:
- ##STR32## wherein Z is --OH;
- and (3) an organic isocyanate compound,
- wherein said phosphorylated polyoxyalkyl polyol, said polyoxyalkyl polyol, and said isocyanate compound are present in a ratio which effectively homogeneously disperses said magnetic powder and securely binds said magnetic powder when coated on said non-magnetic support.
A dispersion of a magnetic powder in a binder, said dispersion consisting essentially of:
- (1) a phosphorylated polyoxyalkyl polyol present in the amount in the range of 5 to 60 percent by weight of the binder and represented by the following formula:
- ##STR33## wherein n.sub.1, n.sub.2 and n.sub.3 may independently be 0 to 10 inclusive and n.sub.4 is 0 or 1
- R.sub.1, R.sub.2, R.sub.3 are independently selected from the group consisting of ##STR34## R.sub.4 is selected from the group consisting of H, --CH.sub.3, --CH.sub.2 --CH.sub.3, --CH.sub.2 --CH.sub.2 --CH.sub.3, ##STR35## X is a dispersing group such as ##STR36## wherein Y.sub.1 and Y.sub.2 are selected from the group consisting of H, Na, Li, K;
- (2) an organic isocyanate compound;
- and
- (3) a vinyl polymer;
- wherein said phosphorylated polyoxyalkyl polyol, said isocyanate compound and said vinyl polymer are present in a ratio which effectively homogeneously disperses said magnetic powder and securely binds said magnetic powder when coated on said non-magnetic support.
A dispersion of a magnetic powder in a binder, said dispersion consisting essentially of:
- (1) a phosphorylated polyoxyalkyl polyol present in an amount in the range of 5 to 60 percent by weight and represented by the following formula:
- ##STR37## wherein n.sub.1, n.sub.2 and n.sub.3 may independently be 0 to 10 inclusive and n.sub.4 is 0 or 1
- R.sub.1, R.sub.2, R.sub.3 are independently selected from the group consisting of ##STR38## R.sub.4 is selected from the group consisting of H, --CH.sub.3, --CH.sub.2 --CH.sub.3, --CH.sub.2 --CH.sub.2 --CH.sub.3, ##STR39## X is a dispersing group such as ##STR40## wherein Y.sub.1 and Y.sub.2 are selected from the group consisting of H, Na, Li, K;
- (2) a polyoxyalkyl polyol represented by the following formula:
- ##STR41## wherein Z is --OH;
- (3) an organic isocyanate compound;
- and
- (4) a vinyl polymer;
- wherein said phosphorylated polyoxyalkyl polyol, said polyoxyalkyl polyol, said isocyanate compound and said vinyl polymer are present in a ratio which effectively homogeneously disperses said magnetic powder and securely binds said magnetic powder when coated on said non-magnetic support.
Dependencies are inferred from the claim text.