A method for forming a composite layer on the surface of an aluminum alloy substrate, comprising the steps of:
- (a) disposing a powder mixture containing a ceramic carbide of a metal, silicon and a metal element which forms with silicon an inter metallic compound having a specific gravity ratio of about 0.7 to about 2.0 relative to said ceramic carbide of a metal upon the surface of said aluminum alloy substrate;
- and:
- (b) irradiating with a laser said power mixture as disposed upon said surface of said aluminum alloy substrate, so as to melt said silicon and said metal element which forms said inter metallic compound with said silicon in said powder mixture and a surface portion of said aluminum alloy substrate and so as to fuse them together.