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AssigneeThe United States of America as represented by the United States Department of Energy
InventorsShih-Ger Chang, David K. Liu, Elizabeth A. Griffiths, David Littlejohn
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The present invention in one aspect relates to a process for the simultaneous removal of NO.sub.x and SO.sub.2 from a fluid stream comprising mixtures thereof and in another aspect relates to the separation, use and/or regeneration of various chemicals contaminated or spent in the process and which includes the steps of: (A) contacting the fluid stream at a temperature of between about 105.degree. and 180.degree. C. with a liquid aqueous slurry or solution comprising an effective amount of an iron chelate of an amino acid moiety having at least one --SH group; (B) separating the fluid stream from the particulates formed in step (A) comprising the chelate of the amino acid moiety and fly ash; (C) washing and separating the particulates of step (B) with an aqueous solution having a pH value of between about 5 to 8; (D) subsequently washing and separating the particulates of step (C) with a strongly acidic aqueous solution having a pH value of between about 1 to 3; (E) washing and separating the particulates of step (D) with an basic aqueous solution having a pH value of between about 9 to 12; (F) optionally adding additional amino acid moiety, iron (II) and alkali to the aqueous liquid from step (D) to produce an aqueous solution or slurry similar to that in step (A) having a pH value of between about 4 to 12; and (G) recycling the aqueous slurry of step (F) to the contacting zone of step (A). Steps (D) and (E) can be carried out in the reverse sequence, however the preferred order is (D) and then (E). In another preferred embodiment the present invention provides a process for the removal of NO.sub.x, SO.sub.2 and particulates from a fluid stream which includes the steps of (A) injecting into a reaction zone an aqueous solution itself comprising (i) an amino acid moiety selected from those described above; (ii) iron (II) ion; and (iii) an alkali, wherein the aqueous solution has a pH of between about 4 and 11; followed by solids separation and washing as is described in steps (B), (C), (D) and (E) above. The overall process is useful to reduce acid rain components from combustion gas sources.
A process of the simultaneous removal of NO.sub.x and SO.sub.2 from a fluid stream itself comprised of NO.sub.x and SO.sub.2, which process comprises:
In a process for removing NO.sub.x and SO.sub.2 from a gas stream containing same by contacting said stream with a mixture of iron (II) chelate of an amino acid moiety having at least one--SH group said amino acid moiety selected from amino acids, N-substituted amino acids, natural peptides and synthetic peptides and an alkali which comprises a basic salt selected from the salts of sodium potassium, lithium, calcium or magnesium to form NO.sub.x and SO.sub.2 contaminated iron (II) amino acid chelate and alkali, the improvement consisting of:
A process for the removal of NO.sub.x, SO.sub.2 and particulates from a fluid stream, which process comprises:
A process for the simultaneous removal of NO.sub.x and SO.sub.2 from a fluid stream comprised of NO.sub.x and SO.sub.2, which process comprises:
A process for the simultaneous removal of NO.sub.x and SO.sub.2 from a fluid stream itself comprised of NO.sub.x and SO.sub.2, which process comprises:
In a process for removing NO.sub.x and SO.sub.2 from a gas stream containing same by contacting said stream with a mixture of iron (II) chelate of an amino acid moiety having at least one--SH group, wherein said amino acid moiety is selected from amino acids, N-substituted amino acids, natural peptides or synthetic peptides, and an alkali wherein said alkali comprises a basic salt selected from the salts of sodium, potassium, lithium, calcium or magnesium, to form NO.sub.x and SO.sub.2 contaminated iron (II) amino acid chelate and alkali, the improvement consisting of:
A process for the removal of NO.sub.x, SO.sub.2 and particulates from fluid stream, which process comprises:
A process for the simultaneous removal of NO.sub.x and SO.sub.2 form a fluid stream comprised of NO.sub.x and SO.sub.2, which process comprises:
Dependencies are inferred from the claim text.