In a process for producing aluminum trihydroxide having a median diameter of less than 4 micrometers with unimodal distribution and minimum deviation comprising the steps of decomposing a supersaturated sodium aluminate solution by adding to said solution an amount of crushed aluminum trihydroxide seed having a BET specific surface area of at least 8 m.sup.2 /g such that the total surface area of said seed is at least 100 m.sup.2 per liter of sodium aluminate solution, and agitating the resulting suspension until a weight ratio of dissolved Al.sub.2 O.sub.3 to caustic Na.sub.2 O of at most 0.7 is obtained, the improvement comprising performing a pre-decomposition process prior to decomposition of the supersaturated sodium aluminate solution to remove impurities from said solution, said pre-decomposition process comprising the steps of
- (a) bringing a supersaturated sodium aluminate solution to be decomposed having a dissolved Na.sub.2 O concentration of between 150 and 250 g/l and a ratio by weight of dissolved Al.sub.2 O.sub.3 to dissolved Na.sub.2 O of between 0.9 and 1.3, together with an amount of crushed aluminum trihydroxide seed having a BET specific surface area of at least 8 m.sup.2 /g in a proportion of from 1 to 10 g of Al.sub.2 O.sub.3 per liter of solution, and agitating said sodium aluminate solution and said seed for a period of from 1 to 3 hours at a temperature between 70.degree. and 90.degree. C. to form a suspension having a liquid phase and a solid phase;
- (b) separating the solid phase, comprising aluminum trihydroxide and impurties, from the liquid phase, comprising supersaturated sodium aluminate solution having a ratio by weight dissolved Al.sub.2 O.sub.3 to dissolved Na.sub.2 O of between 0.8 and 1.2, whereby said supersaturated sodium aluminate solution is substantially free from impurities after said separation.